A review of structures and physical properties of rare earth chalcophosphates

ZX Chen, W Liu, SP Guo - Coordination Chemistry Reviews, 2023 - Elsevier
Metal chalcophosphates are chemically and structurally diverse due to the various
connective ways of phosphorus-sulfur/selenium anionic groups. Rare earth metals have …

KREP2Se6 (RE = Sm, Gd, Tb): The First Rare‐Earth Selenophosphates with Remarkable Nonlinear Optical Activities Realized by Synergistic Effect of RE‐ and P …

ZX Chen, CY Zhao, XH Li, WD Yao, W Liu, SP Guo - Small, 2023 - Wiley Online Library
Rare‐earth (RE) chalcogenides have been extensively studied as infrared nonlinear optical
(NLO) materials because of their nice integrated performances; however, very few RE …

Transuranium Sulfide via the Boron Chalcogen Mixture Method and Reversible Water Uptake in the NaCuTS3 Family

AA Berseneva, VV Klepov, K Pal, K Seeley… - Journal of the …, 2022 - ACS Publications
The behavior of 5f electrons in soft ligand environments makes actinides, and especially
transuranium chalcogenides, an intriguing class of materials for fundamental studies. Due to …

NaREP2Se6 (RE = Y, Sm, Gd–Dy): Quaternary Rare-Earth Selenophosphates with Unique 3D {[REP2Se6]} Framework Built by RESe8 and P2Se6 Motifs …

CY Zhao, ZX Chen, WD Yao, W Zhou, W Liu… - Inorganic …, 2023 - ACS Publications
Rare-earth (RE) chalcophosphates have been widely studied because of their abundant
structures. Here, five new RE selenophosphates, NaREP2Se6 (RE= Y, Sm, Gd–Dy), were …

A series of Rb 4 Ln 2 (P 2 S 6)(PS 4) 2 (Ln= La, Ce, Pr, Nd, Sm, Gd) rare earth thiophosphates with two distinct thiophosphate units [PVS 4] 3− and [P IV 2 S 6] 4−

CK Aslani, LS Breton, VV Klepov, HC Zur Loye - Dalton Transactions, 2021 - pubs.rsc.org
A series of rubidium rare earth thiophosphates with the formula Rb4Ln2 (P2S6)(PS4) 2 (Ln=
La, Ce, Pr, Nd, Sm, and Gd) were synthesized using the high temperature molten flux crystal …

KREP2S6 (RE= Sm, Gd, Tb, Dy): A Series of Polar Rare-Earth Thiophosphates with High Laser-Induced Damage Thresholds and Moderate Nonlinear-Optical …

CY Zhao, WD Yao, MY Li, W Zhou, W Liu… - Inorganic …, 2024 - ACS Publications
As one of the potential candidates of nonlinear-optical (NLO) materials, rare-earth
chalcophosphates have demonstrated promising properties. Here, KREP2S6 (RE= Sm, Gd …

Li3La[PS4]2: The First Lithium Lanthanum Ortho‐Thiophosphate

PL Lange, T Schleid - European Journal of Inorganic Chemistry, 2021 - Wiley Online Library
The first lithium‐containing lanthanum ortho‐thiophosphate (V) with the formula Li3La [PS4]
2 crystallizes orthorhombically in the space group Pbca with a= 1053.51 (6) pm, b= 1920.62 …

Trends in rare earth thiophosphate syntheses: Rb 3 Ln (PS 4) 2 (Ln= La, Ce, Pr), Rb 3− x Na x Ln (PS 4) 2 (Ln= Ce, Pr; x= 0.50, 0.55), and RbEuPS 4 obtained by …

LS Breton, MD Smith, HC zur Loye - CrystEngComm, 2021 - pubs.rsc.org
Single crystals of new rubidium rare earth thiophosphates with the formulas Rb3Ln (PS4) 2
(Ln= La, Ce, Pr), Rb3− xNaxLn (PS4) 2 (Ln= Ce, Pr; x= 0.50, 0.55), and RbEuPS4 were …

Synthesis of Hydrated Ternary Lanthanide-Containing Chlorides Exhibiting X-ray Scintillation and Luminescence

GB Ayer, MD Smith, LG Jacobsohn… - Inorganic …, 2021 - ACS Publications
A series of new ternary lanthanide-based chlorides, Cs2EuCl5 (H2O) 10, Cs7LnCl10 (H2O)
8 (Ln= Gd or Ho), Cs10Tb2Cl17 (H2O) 14 (H3O), Cs2DyCl5 (H2O) 6, Cs8Er3Cl17 (H2O) 25 …

Dimensional reduction upon calcium incorporation in Cs 0.3 (Ca 0.3 Ln 0.7) PS 4 and Cs 0.5 (Ca 0.5 Ln 0.5) PS 4

VV Klepov, V Kocevski, TM Besmann, HC zur Loye - CrystEngComm, 2021 - pubs.rsc.org
Two series of new lanthanide thiophosphates with partial Ca occupancy of the Ln sites, Cs0.
3 (Ca0. 3Ln0. 7) PS4 (Ln= Ce, Pr, Nd, Sm, Gd, Tb, and Dy) and Cs0. 5 (Ca0. 5Ln0. 5) PS4 …