The chemistry of transition metal complexes containing bulky and stable o-carborane unit
has developed greatly in the past few decades. The recent discovery in this field of many …

We have succeeded in synthesizing m-carborane-based chiral NBN-pincer ligands, 1, 7-bis
(oxazolinyl)-1, 7-dicarba-closo-dodecaborane (Carbox)(7− 9). The combination of bis …

Incorporation of one or two o-carborane moieties at the backbone of the pyrazole ring was
achieved by lithiation and nucleophilic addition onto the corresponding 3, 5-dimethyl-1-(2 …

This review summarizes the synthesis and coordination chemistry of a series of carboranyl
ligands containing N, O donors. Such carborane-based ligands are scarcely reported in the …

The synthesis of N, N-bidentate ligands based on a π-deficient N-heterocyclic
pyridylmethylamine core is described. The preparation and characterization of the …

With the rising interest in asymmetric catalysis promoted by earth‐abundant elements, a
chiral ligand will undoubtedly be the most valuable unit of the catalyst. The first proof of …

A series of C-and B-substituted nido-carborane derivatives with a pendant pyridyl group was
prepared. The synthesized compounds were used as ligands in the complexation reactions …

Abstract The novel 2, 6-bis (carborane) pyridine (C 5 H 3 N)(C 2 B 10 H 11) 2 ligand
precursor containing two icosahedral carborane clusters attached to the pyridine ring was …

Azaheterocyclic derivatives of 1, 2-dicarba-closo-dodecaborane (ortho-carborane) are
known to be of particular interest due to numerous plausible applications, particularly, in …

Pyridylmethylamines or pma are versatile platforms for different catalytic transformations.
Five pma‐ligands and their respective Pd complexes have been studied by liquid state …