Tropospheric aqueous-phase chemistry: kinetics, mechanisms, and its coupling to a changing gas phase

H Herrmann, T Schaefer, A Tilgner, SA Styler… - Chemical …, 2015 - ACS Publications
This Review aims to summarize the current understanding of bulk tropospheric aqueous-
phase chemistry. Because a complete review of all developments in this area would be …

Tropospheric OH and HO 2 radicals: field measurements and model comparisons

D Stone, LK Whalley, DE Heard - Chemical Society Reviews, 2012 - pubs.rsc.org
The hydroxyl radical, OH, initiates the removal of the majority of trace gases in the
atmosphere, and together with the closely coupled species, the hydroperoxy radical, HO2, is …

Modeling the processing of aerosol and trace gases in clouds and fogs

B Ervens - Chemical reviews, 2015 - ACS Publications
Aerosol− cloud interactions account for the largest uncertainty in current estimates of
changes in radiative forcing according to the most recent IPCC report. 1 The term “aerosol …

Evaluating the sensitivity of radical chemistry and ozone formation to ambient VOCs and NOx in Bei**g

LK Whalley, EJ Slater… - Atmospheric …, 2021 - acp.copernicus.org
Measurements of OH, HO 2, complex RO 2 (alkene-and aromatic-related RO 2) and total RO
2 radicals taken during the integrated Study of AIR Pollution PROcesses in Bei**g …

Elevated levels of OH observed in haze events during wintertime in central Bei**g

EJ Slater, LK Whalley… - Atmospheric …, 2020 - acp.copernicus.org
Wintertime in situ measurements of OH, HO 2 and RO 2 radicals and OH reactivity were
made in central Bei**g during November and December 2016. Exceptionally elevated NO …

Isoprene emissions in Africa inferred from OMI observations of formaldehyde columns

EA Marais, DJ Jacob, TP Kurosu… - Atmospheric …, 2012 - acp.copernicus.org
We use 2005–2009 satellite observations of formaldehyde (HCHO) columns from the OMI
instrument to infer biogenic isoprene emissions at monthly 1× 1° resolution over the African …

Radical loss in the atmosphere from Cu-Fe redox coupling in aerosols

J Mao, S Fan, DJ Jacob, KR Travis - Atmospheric Chemistry and …, 2013 - acp.copernicus.org
The hydroperoxyl radical (HO 2) is a major precursor of OH and tropospheric ozone. OH is
the main atmospheric oxidant, while tropospheric ozone is an important surface pollutant …

Understanding in situ ozone production in the summertime through radical observations and modelling studies during the Clean air for London project (ClearfLo)

LK Whalley, D Stone, R Dunmore… - Atmospheric …, 2018 - acp.copernicus.org
Measurements of OH, HO 2, RO 2 i (alkene and aromatic-related RO 2) and total RO 2
radicals taken during the ClearfLo campaign in central London in the summer of 2012 are …

Seasonal characteristics of tropical marine boundary layer air measured at the Cape Verde Atmospheric Observatory

LJ Carpenter, ZL Fleming, KA Read, JD Lee… - Journal of Atmospheric …, 2010 - Springer
Observations of the tropical atmosphere are fundamental to the understanding of global
changes in air quality, atmospheric oxidation capacity and climate, yet the tropics are under …

Reporting the sensitivity of Laser Induced Fluorescence instruments used for HO 2 detection to an interference from RO 2 radicals and introducing a novel approach …

LK Whalley, MA Blitz, M Desservettaz… - Atmospheric …, 2013 - amt.copernicus.org
Laboratory studies have revealed that alkene-derived RO 2 and longer-chain alkane-
derived RO 2 (> C 3) radicals rapidly convert to HO 2 and then to OH in the presence of NO …