Frontal polymerizations: from chemical perspectives to macroscopic properties and applications
The synthesis and processing of most thermoplastics and thermoset polymeric materials rely
on energy-inefficient and environmentally burdensome manufacturing methods. Frontal …
on energy-inefficient and environmentally burdensome manufacturing methods. Frontal …
Review on Frontal Polymerization Behavior for Thermosetting Resins: Materials, Modeling and Application
T Luo, Y Ma, X Cui - Polymers, 2024 - mdpi.com
The traditional curing methods for thermosetting resins are energy-inefficient and
environmentally unfriendly. Frontal polymerization (FP) is a self-sustaining process relying …
environmentally unfriendly. Frontal polymerization (FP) is a self-sustaining process relying …
Three-dimensional modeling of frontal polymerization for rapid, efficient, and uniform thermoset composites manufacturing
Due to the incapability of one-dimensional (1D) and two-dimensional (2D) models in
simulating the frontal polymerization (FP) process in laminated composites with multiple …
simulating the frontal polymerization (FP) process in laminated composites with multiple …
Frontal polymerization-assisted 3D printing of short carbon fibers/dicyclopentadiene composites
Discontinuous carbon fibers (d-CFs) with different surface modifications (sizing, carboxyl-
grafting, and norbornene-grafting) were separately dispersed in dicyclopentadiene (DCPD) …
grafting, and norbornene-grafting) were separately dispersed in dicyclopentadiene (DCPD) …
Rapid synchronized fabrication of vascularized thermosets and composites
Bioinspired vascular networks transport heat and mass in hydrogels, microfluidic devices,
self-healing and self-cooling structures, filters, and flow batteries. Lengthy, multistep …
self-healing and self-cooling structures, filters, and flow batteries. Lengthy, multistep …
Rapid multiple-front polymerization of fiber-reinforced polymer composites
Frontal polymerization (FP) is an out-of-autoclave, self-sustaining cure process that enables
rapid and energy-efficient manufacturing of composites compared to conventional …
rapid and energy-efficient manufacturing of composites compared to conventional …
A Mechanism-Based Reaction–Diffusion Model for Accelerated Discovery of Thermoset Resins Frontally Polymerized by Olefin Metathesis
Frontal ring-opening metathesis polymerization (FROMP) involves a self-perpetuating
exothermic reaction, which enables the rapid and energy-efficient manufacturing of …
exothermic reaction, which enables the rapid and energy-efficient manufacturing of …
Multiphysics modeling of frontal polymerization-assisted layer-by-layer additive manufacturing of thermoset polymer components
Frontal polymerization (FP) is a novel curing strategy that relies on a self-propagating
exothermic reaction front to polymerize thermoset resins rapidly. Due to its energy-efficiency …
exothermic reaction front to polymerize thermoset resins rapidly. Due to its energy-efficiency …
Frontal‐Photopolymerization of Fully Biobased Epoxy Composites
C Noè, M Hakkarainen, S Malburet… - Macromolecular …, 2022 - Wiley Online Library
The radical‐induced cationic frontal photopolymerization (RICFP) of fully biobased epoxy
composites is successfully demonstrated. This curing strategy considerably reduces the …
composites is successfully demonstrated. This curing strategy considerably reduces the …
Analytical estimates of front velocity in the frontal polymerization of thermoset polymers and composites
This note presents approximate analytical expressions for the velocity of the self‐
propagating reaction front in the frontal polymerization of thermoset polymers and …
propagating reaction front in the frontal polymerization of thermoset polymers and …