Sulfoximines, sulfondiimides and sulfonimidamides are fascinating but not yet fully explored
variants of the common sulfone or sulfonamide motif. In this study, we report the …

Sulfoximines are emerging as valuable new isosteres for use in medicinal chemistry, with
the potential to modulate physicochemical properties. Recent developments in synthetic …

Dioxazolones are a convenient class of acyl nitrene transfer reagents. Their application in
homogeneous transition-metal catalysis has led to many new amidation reactions …

A new system for NH transfer is developed for the preparation of sulfoximines, which are
emerging as valuable motifs for drug discovery. The protocol employs readily available …

A cationic cobalt (III)‐catalyzed direct C H amidation of unactivated (hetero) arenes and
alkenes by using 1, 4, 2‐dioxazol‐5‐ones as the amidating reagent has been developed …

A procedure for the direct mechanochemical rhodium (III)-catalyzed C–H bond amidation of
arenes with 1, 4, 2-dioxazol-5-ones as the nitrogen source has been developed. The …

The practical aspects of Cp* Rh (III)-catalyzed direct C–H amidation with 1, 4, 2-dioxazol-5-
ones were investigated on the operational safety, use of green solvent, and scalability …

We report a new procedure for the preparation of NH-sulfoximines from sulfides using PIDA
as an oxidant and ammonium carbamate as the ammonia source. Excellent yields were …

Ball milling techniques have been applied in the development of a mechanosynthesis of
[Cp* Co (CO) I2], which proved highly efficient as catalyst in mechanochemical C− H bond …

Sulfoximines are of considerable interest for incorporation into medicinal compounds. A
convenient synthesis of N-protected sulfoximines is achieved, under mild conditions, by …