The global biogeochemical cycle of the rare earth elements

V Hatje, J Schijf, KH Johannesson… - Global …, 2024 - Wiley Online Library
To improve our understanding and guide future studies and applications, we review the
biogeochemistry of the rare earth elements (REE). The REEs, which form a chemically …

Sources, sinks, and cycling of dissolved organic copper binding ligands in the ocean

A Ruacho, C Richon, H Whitby… - Communications Earth & …, 2022 - nature.com
Organic Cu-binding ligands have a fundamental influence on Cu distributions in the global
ocean and they complex> 99% of the dissolved Cu in seawater. Cu-binding ligands …

YREE scavenging in seawater: A new look at an old model

J Schijf, EA Christenson, RH Byrne - Marine Chemistry, 2015 - Elsevier
In the ocean, yttrium and the rare earth elements (YREEs) show nutrient-like vertical profiles.
Since the YREEs have no manifest biological function, their removal from solution …

Implications of ocean acidification on micronutrient elements-iron, copper and zinc, and their primary biological impacts: A review

E Cheriyan, BSK Kumar, GVM Gupta, DB Rao - Marine Pollution Bulletin, 2024 - Elsevier
This review has been undertaken to understand the effectiveness of ocean acidification on
oceanic micronutrient metal cycles (iron, copper and zinc) and its potential impacts on …

[HTML][HTML] Effect of dissolved organic matter on copper bioavailability to a coastal dinoflagellate at environmentally relevant concentrations

E Barber-Lluch, M Nieto-Cid… - Science of the Total …, 2023 - Elsevier
The speciation and bioavailability of copper (Cu) in the marine environment are affected by
the presence of dissolved organic matter (DOM). Previous studies conducted at dissolved …

[HTML][HTML] River-derived humic substances as iron chelators in seawater

R Krachler, RF Krachler, G Wallner, S Hann, M Laux… - Marine chemistry, 2015 - Elsevier
The speciation of iron (III) in oxic seawater is dominated by its hydrolysis and sedimentation
of insoluble iron (III)-oxyhydroxide. As a consequence, many oceanic areas have very low …

Organic complexation of iron in the eastern tropical South Pacific: Results from US GEOTRACES Eastern Pacific Zonal Transect (GEOTRACES cruise GP16)

KN Buck, PN Sedwick, B Sohst, CA Carlson - Marine Chemistry, 2018 - Elsevier
Dissolved iron, organic iron-binding ligands, and organic carbon were determined in full
water column depth profiles across the US GEOTRACES Eastern Pacific Zonal Transect …

Recommendations for best practice for iron speciation by competitive ligand exchange adsorptive cathodic strip** voltammetry with salicylaldoxime

L Mahieu, D Omanović, H Whitby, KN Buck, S Caprara… - Marine Chemistry, 2024 - Elsevier
The method of competitive ligand exchange followed by adsorptive cathodic strip**
voltammetry (CLE-AdCSV) allows for the determination of dissolved iron (DFe) organic …

Evaluation of diffusive gradients in thin films (DGT) technique for speciation of trace metals in estuarine waters-a multimethodological approach

AM Cindrić, S Marcinek, C Garnier, P Salaün… - Science of the total …, 2020 - Elsevier
Understanding the potential bioavailability of trace metals (TM) in marine systems is of prime
importance to implement adapted regulations and efficiently protect our coastal and …

Insights into the bioavailability of oceanic dissolved Fe from phytoplankton uptake kinetics

Y Shaked, KN Buck, T Mellett… - The ISME Journal, 2020 - academic.oup.com
Phytoplankton growth in large parts of the world ocean is limited by low availability of
dissolved iron (dFe), restricting oceanic uptake of atmospheric CO2. The bioavailability of …