Electrochemical CO2 reduction (CO2RR) to multi-carbon products over copper-based catalysts

AR Woldu, Z Huang, P Zhao, L Hu, D Astruc - Coordination Chemistry …, 2022 - Elsevier
Copper has been recognized as the only heterogeneous catalyst leading to the formation of
various products of hydrocarbons and oxygenates, such as ethanol and ethylene, from the …

Construction of C–N bonds from small-molecule precursors through heterogeneous electrocatalysis

J Li, Y Zhang, K Kuruvinashetti… - Nature Reviews Chemistry, 2022 - nature.com
Energy-intensive thermochemical processes within chemical manufacturing are a major
contributor to global CO2 emissions. With the increasing push for sustainability, the scientific …

Operando studies reveal active Cu nanograins for CO2 electroreduction

Y Yang, S Louisia, S Yu, J **, I Roh, C Chen… - Nature, 2023 - nature.com
Carbon dioxide electroreduction facilitates the sustainable synthesis of fuels and chemicals.
Although Cu enables CO2-to-multicarbon product (C2+) conversion, the nature of the active …

Solution-based Cu+ transient species mediate the reconstruction of copper electrocatalysts for CO2 reduction

J Vavra, GPL Ramona, F Dattila, A Kormányos… - Nature Catalysis, 2024 - nature.com
Understanding metal surface reconstruction is of the utmost importance in electrocatalysis,
as this phenomenon directly affects the nature of available active sites. However, its dynamic …

Well-defined diatomic catalysis for photosynthesis of C2H4 from CO2

Z **e, S Xu, L Li, S Gong, X Wu, D Xu, B Mao… - Nature …, 2024 - nature.com
Owing to the specific electronic-redistribution and spatial proximity, diatomic catalysts
(DACs) have been identified as principal interest for efficient photoconversion of CO2 into …

Operando scanning electrochemical probe microscopy during electrocatalysis

C Santana Santos, BN Jaato, I Sanjuán… - Chemical …, 2023 - ACS Publications
Scanning electrochemical probe microscopy (SEPM) techniques can disclose the local
electrochemical reactivity of interfaces in single-entity and sub-entity studies. Operando …

Confined growth of silver–copper Janus nanostructures with {100} facets for highly selective tandem electrocatalytic carbon dioxide reduction

Y Ma, J Yu, M Sun, B Chen, X Zhou, C Ye… - Advanced …, 2022 - Wiley Online Library
Electrocatalytic carbon dioxide reduction reaction (CO2RR) holds significant potential to
promote carbon neutrality. However, the selectivity toward multicarbon products in CO2RR …

Linking the Dynamic Chemical State of Catalysts with the Product Profile of Electrocatalytic CO2 Reduction

J Wang, HY Tan, Y Zhu, H Chu… - Angewandte Chemie, 2021 - Wiley Online Library
The promoted activity and enhanced selectivity of electrocatalysts is commonly ascribed to
specific structural features such as surface facets, morphology, and atomic defects …

Advances and challenges in understanding the electrocatalytic conversion of carbon dioxide to fuels

YY Birdja, E Pérez-Gallent, MC Figueiredo, AJ Göttle… - Nature Energy, 2019 - nature.com
The electrocatalytic reduction of carbon dioxide is a promising approach for storing (excess)
renewable electricity as chemical energy in fuels. Here, we review recent advances and …

The role of in situ generated morphological motifs and Cu(i) species in C2+ product selectivity during CO2 pulsed electroreduction

RM Arán-Ais, F Scholten, S Kunze, R Rizo… - Nature Energy, 2020 - nature.com
The efficient electrochemical conversion of CO2 provides a route to fuels and feedstocks.
Copper catalysts are well-known to be selective to multicarbon products, although the role …