Exploring Stimuli-Responsive Natural Processes for the Fabrication of High-Performance Materials

YL Tan, Y Leow, JH Min Wong, XJ Loh… - …, 2024 - ACS Publications
Climate change and environmental pollution have underscored the urgency for more
sustainable alternatives in synthetic polymer production. Nature's repertoire of biopolymers …

Dityrosine cross-linking in designing biomaterials

BP Partlow, MB Applegate, FG Omenetto… - ACS Biomaterials …, 2016 - ACS Publications
The development of functional biomaterials for tissue engineering and medical applications
has received increasing attention. While it has been known for decades that dityrosine …

Progress in Multiscale Modeling of Silk Materials

HDA Brough, D Cheneler, JG Hardy - Biomacromolecules, 2024 - ACS Publications
As a result of their hierarchical structure and biological processing, silk fibers rank among
nature's most remarkable materials. The biocompatibility of silk-based materials and the …

β-Sheet nanocrystalline domains formed from phosphorylated serine-rich motifs in caddisfly larval silk: a solid state NMR and XRD study

JB Addison, NN Ashton, WS Weber… - …, 2013 - ACS Publications
Adhesive silks spun by aquatic caddisfly (order Trichoptera) larvae are used to build both
intricate protective shelters and food harvesting nets underwater. In this study, we use 13C …

Self-Tensioning Aquatic Caddisfly Silk: Ca2+-Dependent Structure, Strength, and Load Cycle Hysteresis

NN Ashton, DR Roe, RB Weiss… - …, 2013 - ACS Publications
Caddisflies are aquatic relatives of silk-spinning terrestrial moths and butterflies. Casemaker
larvae spin adhesive silk fibers for underwater construction of protective composite cases …

Peroxinectin catalyzed dityrosine crosslinking in the adhesive underwater silk of a casemaker caddisfly larvae, Hysperophylax occidentalis

CS Wang, NN Ashton, RB Weiss, RJ Stewart - Insect biochemistry and …, 2014 - Elsevier
Aquatic caddisfly larvae use sticky silk fibers as an adhesive tape to construct protective
composite structures under water. Three new silk fiber components were identified by …

Silk tape nanostructure and silk gland anatomy of trichoptera

NN Ashton, DS Taggart, RJ Stewart - Biopolymers, 2012 - Wiley Online Library
Caddisflys (order Trichoptera) construct elaborate protective shelters and food harvesting
nets with underwater adhesive silk. The silk fiber resembles a nanostructured tape …

Aquatic caddisworm silk is solidified by environmental metal ions during the natural fiber‐spinning process

NN Ashton, RJ Stewart - The FASEB Journal, 2019 - Wiley Online Library
Aquatic caddisfly larvae (caddisworms) wet‐spin fibers to construct composite cases of silk
and stone. The silk emerges from labial ducts as a nanofibrous fluid gel, flowing over the …

Reversible assembly of β-sheet nanocrystals within caddisfly silk

JB Addison, WS Weber, Q Mou, NN Ashton… - …, 2014 - ACS Publications
Nuclear magnetic resonance (NMR) and X-ray diffraction (XRD) experiments reveal the
structural importance of divalent cation–phosphate complexes in the formation of β-sheet …

Research on possible medical use of silk produced by caddisfly larvae of Hydropsyche angustipennis (Trichoptera, Insecta)

M Tszydel, A Zabłotni, D Wojciechowska… - journal of the …, 2015 - Elsevier
Silk products are used in medicine as biomaterials, and are particularly promising as
scaffolds in tissue engineering. To date only silkworm and spider silk medical potential has …