Environmental Implications of Hydroxyl Radicals (OH)

S Gligorovski, R Strekowski, S Barbati… - Chemical reviews, 2015 - ACS Publications
The hydroxyl radical (• OH) is one of the most powerful oxidizing agents, able to react
unselectively and instantaneously with the surrounding chemicals, including organic …

Atmospheric degradation of volatile organic compounds

R Atkinson, J Arey - Chemical reviews, 2003 - ACS Publications
Volatile organic compounds (VOCs) are emitted into the atmosphere from anthropogenic
and biogenic sources, 1-5 and may also be formed in situ in the atmosphere as products of …

Indoor air quality implications of germicidal 222 nm light

VP Barber, MB Goss, LJ Franco Deloya… - Environmental …, 2023 - ACS Publications
One strategy for mitigating the indoor transmission of airborne pathogens, including the
SARS-CoV-2 virus, is irradiation by germicidal UV light (GUV). A particularly promising …

Protocol for the development of the Master Chemical Mechanism, MCM v3 (Part A): tropospheric degradation of non-aromatic volatile organic compounds

SM Saunders, ME Jenkin, RG Derwent… - … Chemistry and Physics, 2003 - acp.copernicus.org
Kinetic and mechanistic data relevant to the tropospheric degradation of volatile organic
compounds (VOC), and the production of secondary pollutants, have previously been used …

Modelling the evolution of organic carbon during its gas-phase tropospheric oxidation: development of an explicit model based on a self generating approach

B Aumont, S Szopa, S Madronich - Atmospheric Chemistry and …, 2005 - acp.copernicus.org
Organic compounds emitted in the atmosphere are oxidized in complex reaction sequences
that produce a myriad of intermediates. Although the cumulative importance of these organic …

The heterogeneous reaction of hydroxyl radicals with sub-micron squalane particles: a model system for understanding the oxidative aging of ambient aerosols

JD Smith, JH Kroll, CD Cappa, DL Che… - Atmospheric …, 2009 - acp.copernicus.org
The heterogeneous reaction of OH radicals with sub-micron squalane particles, in the
presence of O 2, is used as a model system to explore the fundamental chemical …

Isoprene oxidation by nitrate radical: alkyl nitrate and secondary organic aerosol yields

AW Rollins, A Kiendler-Scharr, JL Fry… - Atmospheric …, 2009 - acp.copernicus.org
Alkyl nitrates and secondary organic aerosol (SOA) produced during the oxidation of
isoprene by nitrate radicals has been observed in the SAPHIR (Simulation of Atmospheric …

Role of hydrogen-bonded intermediates in the bimolecular reactions of the hydroxyl radical

IWM Smith, AR Ravishankara - The Journal of Physical Chemistry …, 2002 - ACS Publications
Because of their importance in atmospheric and combustion chemistry, the rate coefficients
and mechanisms of gas-phase reactions of the OH radical have been studied extensively …

A comprehensive and compact n-heptane oxidation model derived using chemical lum**

SS Ahmed, F Mauß, G Moréac, T Zeuch - Physical Chemistry Chemical …, 2007 - pubs.rsc.org
A detailed reaction mechanism for n-heptane oxidation has been compiled and
subsequently simplified. The model is based on a kinetic model for C1–C4 fuel oxidation of …

Heterogeneous chemistry and reaction dynamics of the atmospheric oxidants, O 3, NO 3, and OH, on organic surfaces

RC Chapleski, Y Zhang, D Troya… - Chemical Society Reviews, 2016 - pubs.rsc.org
Heterogeneous chemistry of the most important atmospheric oxidants, O3, NO3, and OH,
plays a central role in regulating atmospheric gas concentrations, processing aerosols, and …