Metal–organic cages (MOCs) are discrete, supramolecular entities that consist of metal
nodes and organic linkers, which can offer solution processability and high porosity …

High symmetry metallosupramolecular architectures (MSAs) have been exploited for a
range of applications including molecular recognition, catalysis and drug delivery. Recently …

Chiral lanthanide cages with circularly polarized luminescence (CPL) properties have found
potential application in enantioselective guest recognition and sensing. However, it still …

The expression of biological functions, such as enzyme catalysis, immune response, and
cargo transport in confined nanospaces, with very different physical and chemical …

Charge plays a crucial role in the function of molecular and supramolecular systems, but
coordination hosts capable of orthogonal charge regulation remain elusive so far. In this …

Post‐synthetic modification (PSM) is an effective approach for the tailored functionalization
of metal‐organic architectures, but its generalizability remains challenging. Herein we report …

The field of metallosupramolecular chemistry has advanced rapidly in recent years. Much
work in this area has focused on the formation of hollow self-assembled metal-organic …

Precise control over guest release and recapture using external stimuli is a valuable goal,
potentially enabling new modes of chemical purification. Including redox moieties within the …

Metal-organic cages (MOCs) represent a tantalizing class of metal-organic materials
(MOMs) in terms of host-guest binding ability related to their well-defined cavities and …

Developments in the confinement of phosphines within micro-or nano-environments are
explored. Phosphines are ubiquitous across metal coordination chemistry and underpin …