Generating catalytic sites in UiO-66 through defect engineering

X Feng, HS Jena, C Krishnaraj, K Leus… - … Applied Materials & …, 2021 - ACS Publications
UiO-66 is regarded as an epitome of metal–organic frameworks (MOFs) because of its
stability. Defect engineering has been used as a toolbox to alter the performance of MOFs …

The chemistry and applications of hafnium and cerium (IV) metal–organic frameworks

Z Hu, Y Wang, D Zhao - Chemical Society Reviews, 2021 - pubs.rsc.org
The coordination connection of organic linkers to the metal clusters leads to the formation of
metal–organic frameworks (MOFs), where the metal clusters and ligands are spatially …

Catalysis by metal organic frameworks: perspective and suggestions for future research

D Yang, BC Gates - Acs Catalysis, 2019 - ACS Publications
Metal organic frameworks (MOFs) have drawn wide attention as potential catalysts, offering
high densities of catalytic sites in high-area porous solids, some with stabilities at high …

A decade of UiO-66 research: a historic review of dynamic structure, synthesis mechanisms, and characterization techniques of an archetypal metal–organic …

J Winarta, B Shan, SM Mcintyre, L Ye… - Crystal Growth & …, 2019 - ACS Publications
UiO-66 is an archetypal metal–organic framework (MOF) with a very high surface area as
well as high thermal stability. It is found that the stability can be attributed to the metal oxide …

Imaging defects and their evolution in a metal–organic framework at sub-unit-cell resolution

L Liu, Z Chen, J Wang, D Zhang, Y Zhu, S Ling… - Nature …, 2019 - nature.com
Defect engineering of metal–organic frameworks (MOFs) offers promising opportunities for
tailoring their properties to specific functions and applications. However, determining the …

Metal-organic frameworks with carboxyl functionalized channels as multifunctional ion-conductive interphase for highly reversible Zn anode

WL **n, J **ao, J Li, L Zhang, H Peng, Z Yan… - Energy Storage …, 2023 - Elsevier
Aqueous zinc batteries are promising for large-scale energy storage. However, the cycle
stability of the Zn anode is severely hindered by the continuous side reactions and …

Surface-supported metal–organic framework thin films: fabrication methods, applications, and challenges

J Liu, C Wöll - Chemical Society Reviews, 2017 - pubs.rsc.org
Surface-supported metal–organic framework thin films are receiving increasing attention as
a novel form of nanotechnology. New deposition techniques that enable the control of the …

Defect engineering: tuning the porosity and composition of the metal–organic framework UiO-66 via modulated synthesis

GC Shearer, S Chavan, S Bordiga, S Svelle… - Chemistry of …, 2016 - ACS Publications
Presented in this paper is a deep investigation into the defect chemistry of UiO-66 when
synthesized in the presence of monocarboxylic acid modulators under the most commonly …

Enhanced selectivity in mixed matrix membranes for CO2 capture through efficient dispersion of amine-functionalized MOF nanoparticles

B Ghalei, K Sakurai, Y Kinoshita, K Wakimoto… - Nature Energy, 2017 - nature.com
Mixed matrix membranes (MMMs) for gas separation applications have enhanced selectivity
when compared with the pure polymer matrix, but are commonly reported with low intrinsic …

Defect‐engineered metal–organic frameworks

Z Fang, B Bueken, DE De Vos… - Angewandte Chemie …, 2015 - Wiley Online Library
Defect engineering in metal–organic frameworks (MOFs) is an exciting concept for tailoring
material properties, which opens up novel opportunities not only in sorption and catalysis …