Metal–Organic Frameworks with Low‐Valent Metal Nodes
RE Sikma, KP Balto, JS Figueroa… - Angewandte Chemie …, 2022 - Wiley Online Library
Metal–organic frameworks (MOFs) are crystalline, 2‐and 3‐dimensional coordination
polymers formed by bonding interactions between metals and multitopic organic ligands …
polymers formed by bonding interactions between metals and multitopic organic ligands …
Bridging Homogeneous and Heterogeneous Catalysis: Phosphine‐Functionalized Metal‐Organic Frameworks
Phosphine‐functionalized metal‐organic frameworks (P‐MOFs) as an emerging class of
coordination polymers, have provided novel opportunities for the development of …
coordination polymers, have provided novel opportunities for the development of …
Cavity-Shape-Dependent Divergent Chemical Reaction inside Aqueous Pd6L4 Cages
Chemical reactions inside the confined pockets of enzyme-mimicking hosts, such as cages
and macrocycles, have been an emerging field of interest over the past decade. Although …
and macrocycles, have been an emerging field of interest over the past decade. Although …
Catalytic asymmetric P–H insertion reactions
X Gu, X Mo, WJ Bai, P **e, W Hu… - Journal of the American …, 2023 - ACS Publications
Albeit notable endeavors in enantioselective carbene insertion into X–H bonds (X= C, O, N,
S, Si, B), the catalytic asymmetric P–H insertion reactions still stand for a long-lasting …
S, Si, B), the catalytic asymmetric P–H insertion reactions still stand for a long-lasting …
Heterogenized Molecular Rhodium Phosphine Catalysts within Metal–Organic Frameworks for Alkene Hydroformylation
Molecularly defined organometallic rhodium phosphine complexes were efficiently
heterogenized within a MOF structure without affecting neither their molecular nature nor …
heterogenized within a MOF structure without affecting neither their molecular nature nor …
An Inorganic Click Reaction for the Synthesis of Interlocked Molecules
A Mapp, JT Wilmore, PD Beer… - Angewandte …, 2023 - Wiley Online Library
We describe the use of the cyaphide‐azide 1, 3‐dipolar cycloaddition reaction for the
synthesis of a new class of inorganic rotaxanes containing gold (I) triazaphosphole stoppers …
synthesis of a new class of inorganic rotaxanes containing gold (I) triazaphosphole stoppers …
Propeller ultralong room temperature phosphorescence: new aspect of triphenylphosphine derivatives
W Gao, X Dai, C Hou, W Sun, Q Gong… - Advanced Optical …, 2023 - Wiley Online Library
Triphenylphosphine (Ph3P) derivatives are used as indispensable ligands in catalytic
chemistry, as represented by Crab‐tree's catalyst, Wilkinson's catalyst, and Grubbs' catalyst …
chemistry, as represented by Crab‐tree's catalyst, Wilkinson's catalyst, and Grubbs' catalyst …
An Isolable Triarylphosphine Radical Cation Electronically Stabilized by Through-Space Radical Delocalization
Synthesis and characterization of a thermally stable triarylphosphine radical cation,[P (8-Br-
C10H6) 3][BArF24]([1][BArF24], BArF24= tetrakis (3, 5-bis (trifluoromethyl) phenyl) borate) …
C10H6) 3][BArF24]([1][BArF24], BArF24= tetrakis (3, 5-bis (trifluoromethyl) phenyl) borate) …
Constructing an acidic microenvironment by sulfonated polymers for photocatalytic reduction of hexavalent chromium under neutral conditions
C Zhang, Q Zhuang, H Wang, X Ying, R Ji… - Journal of Colloid and …, 2023 - Elsevier
Hexavalent chromium (VI) heavy metal contamination is considered a serious threat to
human health and the environment. The photocatalytic reduction of Cr (VI) basically occurs …
human health and the environment. The photocatalytic reduction of Cr (VI) basically occurs …
Synthesis of a rhodium (iii) dinitrogen complex using a calix [4] arene-based diphosphine ligand
Synthesis of a rhodium( iii ) dinitrogen complex using a calix[4]arene-based diphosphine ligand
- Chemical Communications (RSC Publishing) DOI:10.1039/D2CC06837K Royal Society of …
- Chemical Communications (RSC Publishing) DOI:10.1039/D2CC06837K Royal Society of …