Vibrational sum-frequency generation hyperspectral microscopy for molecular self-assembled systems

H Wang, W **ong - Annual Review of Physical Chemistry, 2021 - annualreviews.org
In this review, we discuss the recent developments and applications of vibrational sum-
frequency generation (VSFG) microscopy. This hyperspectral imaging technique can resolve …

Structure of the Silica/Divalent Electrolyte Interface: Molecular Insight into Charge Inversion with Increasing pH

M Rashwan, B Rehl, A Sthoer… - The Journal of …, 2020 - ACS Publications
The molecular origin of overcharging at mineral oxide surfaces remains a cause of
contention within the geochemistry, physics, and colloidal chemistry communities owing to …

Liquid flow reversibly creates a macroscopic surface charge gradient

P Ober, WQ Boon, M Dijkstra, EHG Backus… - Nature …, 2021 - nature.com
The charging and dissolution of mineral surfaces in contact with flowing liquids are
ubiquitous in nature, as most minerals in water spontaneously acquire charge and dissolve …

Efficient quantum vibrational spectroscopy of water with high-order path integrals: From bulk to interfaces

S Shepherd, J Lan, DM Wilkins… - The Journal of Physical …, 2021 - ACS Publications
Vibrational spectroscopy is key in probing the interplay between the structure and dynamics
of aqueous systems. To map different regions of experimental spectra to the microscopic …

Influence of the hydrogen-bonding environment on vibrational coupling in the electrical double layer at the silica/aqueous interface

S Parshotam, B Rehl, F Busse, A Brown… - The Journal of …, 2022 - ACS Publications
Vibrational spectroscopy is a powerful tool for determining the local hydrogen-bonding
environment. However, vibrational coupling present in H2O makes it difficult to relate …

Intermolecular interactions at the silica–liquid interface modulate the fermi resonance coupling in surface methanol

TT Bui, LA Colón, L Velarde - The Journal of Physical Chemistry …, 2021 - ACS Publications
The buried solid/liquid interface between hydrophilic fused silica and binary solvent mixtures
of acetonitrile (MeCN) and methanol (MeOH) was studied with vibrational sum-frequency …

Structure and sum-frequency generation spectra of water on uncharged Q 4 silica surfaces: a molecular dynamics study

KS Smirnov - Physical Chemistry Chemical Physics, 2020 - pubs.rsc.org
The structural characteristics and sum-frequency generation (SFG) spectra of water near
neutral Q4 silica surfaces were investigated by molecular dynamics simulations. The …

Influence of Charged Site Density on Local Electric Fields and Polar Solvent Organization at Oxide Interfaces

S Dadashi, S Parshotam, B Mandal… - The Journal of …, 2024 - ACS Publications
The characteristics of oxide surfaces such as their hydroxyl density, the associated acid–
base chemistry, and the resulting surface charge play a crucial role in modulating the …

Application of the approximate 3D-reference interaction site model (RISM) molecular solvation theory to acetonitrile as solvent

D Roy, A Kovalenko - The Journal of Physical Chemistry B, 2020 - ACS Publications
The integral equation formalism based reference interaction site model (RISM) molecular
solvation theory is applied to pure liquid acetonitrile and water–acetonitrile binary mixtures …

On the Differences in the Mechanisms of Adsorption of Aromatic Heterocycles from Water–Acetonitrile Solutions on Octadecyl-Bonded Silica Gels

BR Saifutdinov, AK Buryak - Colloid Journal, 2019 - Springer
Abstract Adsorption of some 1, 3, 4-oxadiazoles and 1, 2, 4, 5-tetrazines from water–
acetonitrile solutions on Luna C 18 and Discovery C 18 silica gels with grafted octadecyl …