Proton transport in metal–organic frameworks

DW Lim, H Kitagawa - Chemical reviews, 2020 - ACS Publications
Solid-state proton conductors (SSPCs), which are a key component for the safety and
efficiency of fuel cells, have received much attention due to their broad application in …

Recent advances in the development of electronically and ionically conductive metal-organic frameworks

G Zhang, L **, R Zhang, Y Bai, R Zhu… - Coordination Chemistry …, 2021 - Elsevier
As porous materials, metal–organic frameworks (MOFs) have drawn increased attention and
are widely applied in various fields such as catalysis, gas/energy storage, chemical sensing …

Copper (I)–iodide cluster structures as functional and processable platform materials

J Troyano, F Zamora, S Delgado - Chemical Society Reviews, 2021 - pubs.rsc.org
The combination of the copper (I)–iodide entity with organic ligands gives rise to a large
variety of CuII polynuclear structures in the form of molecular complexes or extended …

Superprotonic Conductivity of MOFs and Other Crystalline Platforms Beyond 10−1 S cm−1

SC Pal, MC Das - Advanced Functional Materials, 2021 - Wiley Online Library
The proton‐exchange membrane (PEM) is a fundamental module of proton‐exchange
membrane fuel cells (PEMFCs), permitting proton passage and thus governing the overall …

High proton conductivity achieved by encapsulation of imidazole molecules into proton-conducting MOF-808

HB Luo, Q Ren, P Wang, J Zhang… - ACS applied materials …, 2019 - ACS Publications
Metal–organic frameworks (MOFs), as newly emerging materials, show compelling intrinsic
structural features, eg, the highly crystalline nature and designable and tunable porosity, as …

Strategies for designing metal–organic frameworks with superprotonic conductivity

A Sharma, J Lim, MS Lah - Coordination Chemistry Reviews, 2023 - Elsevier
The use of metal ions and organic linkers to generate metal–organic frameworks (MOFs)
with various functionalities, porosity, and dimensionality has attracted the attention of …

Proton-conductive channels engineering of perfluorosulfonic acid membrane via in situ acid–base pair of metal organic framework for fuel cells

W Zhang, S Zhao, R Wang, A Zhang, Y Huang… - … Composites and Hybrid …, 2023 - Springer
The development of rapid and dependable proton transport channels is crucial for proton
exchange membrane fuel cells (PEMFCs) operating in low humidity conditions. Herein, a …

Coordination polymer-based conductive materials: ionic conductivity vs. electronic conductivity

HN Wang, X Meng, LZ Dong, Y Chen, SL Li… - Journal of Materials …, 2019 - pubs.rsc.org
Coordination polymers (CPs) are emerging crystalline materials, and researchers have
promoted their potential applications in various fields owing to their easily designed and …

Metal–Organic Frameworks and Other Crystalline Materials for Ultrahigh Superprotonic Conductivities of 10−2 S cm−1 or Higher

S Chand, SM Elahi, A Pal… - Chemistry–A European …, 2019 - Wiley Online Library
Proton‐conducting materials in the solid state have received immense attention for their role
as electrolytes in proton‐exchange membrane fuel cells. Recently, crystalline materials …

Achieving efficient proton conduction in a MOF-based proton exchange membrane through an encapsulation strategy

YY Cai, Q Yang, ZY Zhu, QH Sun, AM Zhu… - Journal of Membrane …, 2019 - Elsevier
Metal-organic frameworks (MOFs) have attracted immense attention in the field of proton-
conducting materials due to their high tunability and designability. Although considerable …