Metal–organic framework magnets

AE Thorarinsdottir, TD Harris - Chemical reviews, 2020 - ACS Publications
Metal–organic frameworks represent the ultimate chemical platform on which to develop a
new generation of designer magnets. In contrast to the inorganic solids that have dominated …

Structure and magnetism of coordination polymers containing dicyanamide and tricyanomethanide

SR Batten, KS Murray - Coordination Chemistry Reviews, 2003 - Elsevier
Coordination polymers containing dicyanamide (N (CN) 2−, dca) or tricyanomethanide (C
(CN) 3−, tcm) bridging ligands are described from the perspective of their structure and …

Designer magnets containing cyanides and nitriles

JS Miller, JL Manson - accounts of chemical research, 2001 - ACS Publications
Magnets synthesized from molecules have contributed to the renaissance in the study of
magnetic materials. Three-dimensional network solids exhibiting magnetic ordering have …

Topology of interpenetration

SR Batten - CrystEngComm, 2001 - pubs.rsc.org
Recent examples of interpenetrating and self-penetrating networks are highlighted in a
discussion of interpenetration topology. A web site (http://web. chem. monash. edu …

Molecular geometry directed kagomé and honeycomb networks: toward two-dimensional crystal engineering

S Furukawa, H Uji-i, K Tahara, T Ichikawa… - Journal of the …, 2006 - ACS Publications
We present here the formation of a molecular Kagomé network within a two-dimensional
(2D) crystal on a surface. This system provides a clear example of how, by design, molecular …

A Structurally Perfect S = 1/2 Metal−Organic Hybrid Kagomé Antiferromagnet

EA Nytko, JS Helton, P Müller… - Journal of the American …, 2008 - ACS Publications
We report the synthesis and magnetic characterization of Cu (1, 3-bdc)(1, 3-bdc= 1, 3-
benzenedicarboxylate), a novel structurally perfect S= 1/2 metal− organic hybrid kagomé …

Probing magnetic interactions in metal–organic frameworks and coordination polymers microscopically

PJ Saines, NC Bristowe - Dalton Transactions, 2018 - pubs.rsc.org
Materials with magnetic interactions between their metal centres play a tremendous role in
modern technologies and can exhibit unique physical phenomena. In recent years …

Hydrothermal Synthesis, Structural Chemistry, and Magnetic Properties of Materials of the MII/Triazolate/Anion Family, Where MII = Mn, Fe, and Ni

W Ouellette, AV Prosvirin, J Valeich… - Inorganic …, 2007 - ACS Publications
Hydrothermal chemistry has been exploited in the preparation of a series of manganese (II),
iron (II), and nickel (II) triazolate frameworks,[Mn7 (trz) 8 (CH3CO2) 4 (OH) 2]⊙ 2.5 H2O (1⊙ …

The chemistry and complexes of small cyano anions

DR Turner, ASR Chesman, KS Murray… - Chemical …, 2011 - pubs.rsc.org
The chemistry of the anions dicyanamide and tricyanomethanide (dca and tcm, respectively)
has produced a plethora of discoveries over the past few decades, particularly in relation to …

Metal− Metal Bonded Diruthenium (II, III) Assemblies with the Polycyano Anionic Linkers N (CN) 2-, C (CN) 3-, and 1, 4-Dicyanamido-2, 5-dimethylbenzene (DM …

H Miyasaka, R Clerac, CS Campos-Fernandez… - Inorganic …, 2001 - ACS Publications
The new metal− metal bonded diruthenium (II, III) compounds [Ru2 (O2CCH3) 4 (μ-L)]∞(L=
N (CN) 2-, 1; C (CN) 3-, 2) and [{Ru2 (O2CCH3) 2 (mhp) 2} 2 (μ-DM-Dicyd)](3)(mhp= 2-oxy-6 …