Exploring the Reaction Mechanism of Heterobimetallic Nickel‐Alkali Catalysts for Ethylene Polymerization: Secondary‐Metal‐Ligand Cooperative Catalysis

P Apilardmongkol, M Ratanasak, J Hasegawa… - …, 2022 - Wiley Online Library
In this work, we explored the reaction mechanism of heterobimetallic nickel
phenoxyphosphine polyethylene glycol (Ni‐PEG) with alkali metals (M+= Li+, Na+, K+, and …

Monometallic and heterobimetallic ruthenium (II) and palladium (II) complexes based on a pyridine‐hydrazone ligand as bifunctional catalysts for ROMP of …

PDS Gois, JIP Maia, GHC Masson… - Applied …, 2022 - Wiley Online Library
The monometallic complex [Pd (L)(PPh3)](mono‐Pd) was synthesized using a potentially
tridentate hydrazone (H2L) and used as precursor to prepare a heterobimetallic ruthenium …

DOUBLE COMPLEX SALTS OF NICKEL AMINES WITH THE [RuNOCl5]2– ANION: SYNTHESIS, STRUCTURE, PROPERTIES

AO Borodin, NV Kuratieva, PE Plyusnin… - Journal of Structural …, 2022 - Springer
Two new double complex salts [Ni (NH3) 6][RuNOCl5] and [Ni (en) 3][RuNOCl5] are
prepared and structurally characterized. The structure of both compounds is formed by [Ni …

Ru/Pd Complex and Its Monometallic Fragments as Catalysts for Norbornene Polymerization via ROMP and Addition

TR Cruz, GHC Masson, KAE Amorim, AEH Machado… - Catalysts, 2022 - mdpi.com
The [Ru (PPh3) 2Cl-piperidine (4-aminomethyl)] complex (mono-Ru) was synthesized from
[Ru (PPh3) 3Cl2] and 4-(aminomethyl) piperidine, whereas the [(PPh3) PdCl (Shiff-pip)] …

New Double Complex Salts [M(im)n][RuNOCl5] (M = Ni, Cu): Synthesis, Structure, and Thermal Properties

AO Borodin, EY Filatov, PE Plusnin… - Russian Journal of …, 2024 - Springer
Procedures for the synthesis of new double complex salts [Cu (im) 4][RuNOCl5],[Ni (im)
6][RuNOCl5]· H2O, and p-[Ni (im) 4 (DMF) 2][RuNOCl5] have been developed and their …

[PDF][PDF] A Constructive Model To Demonstrate the Relationship Between the Effectiveness of Training Programs, Assistive Technology, and the Working Environment …

A Albulayhi - Inf. Sci. Lett., 2022 - digitalcommons.aaru.edu.jo
The study's goal was to evaluate a structural model that incorporates training variables and
workplace variables in the Kingdom of Saudi Arabia: Buraidah and Al Majma'ah cities. The …

Complexos heterobimetálicos de RuII-PdII como catalisadores multifuncionais de reações mecanisticamente distintas: Heck, ROMP e polimerização vinílica

TR Cruz - 2024 - repositorio.unesp.br
A integração de dois centros metálicos em complexos heterobimetálicos oferece
versatilidade para aplicação em catálise homogênea. Para explorar essas vantagens, duas …

Complexos bimetálicos de rutênio (II) e paládio (II): acoplamento de reações mecanisticamente distintas usando catalisadores multifuncionais via catálise tandem

PDS Gois - 2024 - repositorio.unesp.br
A primeira parte deste trabalho, aborda a síntese do complexo monometálico [Pd
(DMISO)(PPh3)](mono-Pd) utilizando uma hidrazona tridentada (H2DMISO) reagindo com …

Theoretical study of ethylene polymerization by phenoxy-imine catalyst

P Apilardmongkol - 2021 - digital.car.chula.ac.th
Reaction mechanisms of ethylene polymerization catalyzed by the phenoxy-imine (FI) and
the nickel phenoxyphosphine polyethylene glycol (Ni-PEG) with alkali metals were explored …

[PDF][PDF] Síntese de copolímeros pelo acoplamento da polimerização via adição e metátese de olefinas de norborneno por um catalisador heterobimetálico de Ni (II)/Ru …

DHN Santos - 2023 - repositorio.unesp.br
Com a necessidade de novos materiais poliméricos que pudessem satisfazer os avanços
das tecnologias, a busca por polímeros com propriedades e arquiteturas sofisticadas tem se …