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Chemical flexibility of atomically precise metal clusters
S Li, NN Li, XY Dong, SQ Zang, TCW Mak - Chemical Reviews, 2024 - ACS Publications
Ligand-protected metal clusters possess hybrid properties that seamlessly combine an
inorganic core with an organic ligand shell, imparting them exceptional chemical flexibility …
inorganic core with an organic ligand shell, imparting them exceptional chemical flexibility …
N-Heterocyclic Carbene-Stabilized Atomically Precise Metal Nanoclusters
EL Albright, TI Levchenko, VK Kulkarni… - Journal of the …, 2024 - ACS Publications
This perspective highlights advances in the preparation and understanding of metal
nanoclusters stabilized by organic ligands with a focus on N-heterocyclic carbenes (NHCs) …
nanoclusters stabilized by organic ligands with a focus on N-heterocyclic carbenes (NHCs) …
Near-unity NIR phosphorescent quantum yield from a room-temperature solvated metal nanocluster
WQ Shi, L Zeng, RL He, XS Han, ZJ Guan, M Zhou… - Science, 2024 - science.org
Metal nanoclusters have emerged as promising near-infrared (NIR)–emissive materials, but
their room-temperature photoluminescence quantum yield (PLQY), especially in solution, is …
their room-temperature photoluminescence quantum yield (PLQY), especially in solution, is …
Surface and interface coordination chemistry learned from model heterogeneous metal nanocatalysts: from atomically dispersed catalysts to atomically precise …
The surface and interface coordination structures of heterogeneous metal catalysts are
crucial to their catalytic performance. However, the complicated surface and interface …
crucial to their catalytic performance. However, the complicated surface and interface …
Recent advances in the chemistry and applications of N-heterocyclic carbenes
N-Heterocyclic carbenes, despite being isolated and characterized three decades ago, still
capture scientists' interest as versatile, modular and strongly coordinating moieties. In the …
capture scientists' interest as versatile, modular and strongly coordinating moieties. In the …
Suppression of kernel vibrations by layer-by-layer ligand engineering boosts photoluminescence efficiency of gold nanoclusters
The restriction of structural vibration has assumed great importance in attaining bright
emission of luminescent metal nanoclusters (NCs), where tremendous efforts are devoted to …
emission of luminescent metal nanoclusters (NCs), where tremendous efforts are devoted to …
Visible to NIR‐II Photoluminescence of Atomically Precise Gold Nanoclusters
Atomically precise gold nanoclusters (NCs) have emerged as a new class of precision
materials and attracted wide interest in recent years. One of the unique properties of such …
materials and attracted wide interest in recent years. One of the unique properties of such …
N-Heterocyclic carbenes as tunable ligands for catalytic metal surfaces
Heterogeneous catalysts represent the backbone of many industrial processes and thus
have a considerable societal impact. The active sites of these heterogeneous catalysts are …
have a considerable societal impact. The active sites of these heterogeneous catalysts are …
N-Heterocyclic Carbene-Stabilized Hydrido Au24 Nanoclusters: Synthesis, Structure, and Electrocatalytic Reduction of CO2
Atomically precise hydrido gold nanoclusters are extremely rare but interesting due to their
potential applications in catalysis. By optimization of molecular precursors, we have …
potential applications in catalysis. By optimization of molecular precursors, we have …
Two triplet emitting states in one emitter: Near-infrared dual-phosphorescent Au20 nanocluster
Intrinsic dual-emission (DE) of gold nanoclusters in the near-infrared (NIR) are fascinating
for fundamental importance and practical applications, but their synthesis remains a …
for fundamental importance and practical applications, but their synthesis remains a …