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Mechanochemical tools for polymer materials
Mechanochemistry provides a unique approach to investigate macroscopic deformation,
failure and healing of polymer materials. The development of mechanophores–molecular …
failure and healing of polymer materials. The development of mechanophores–molecular …
From molecules to polymers—harnessing inter‐and intramolecular interactions to create mechanochromic materials
The development of mechanophores as building blocks that serve as predefined weak
linkages has enabled the creation of mechanoresponsive and mechanochromic polymer …
linkages has enabled the creation of mechanoresponsive and mechanochromic polymer …
Azobenzene as a photoswitchable mechanophore
Azobenzene has been widely explored as a photoresponsive element in materials science.
Although some studies have investigated the force-induced isomerization of azobenzene …
Although some studies have investigated the force-induced isomerization of azobenzene …
Fast, reversible mechanochromism of regioisomeric oxazine mechanophores: Develo** in situ responsive force probes for polymeric materials
To address hysteretic or irreversible mechanochromism found in most bond-scission-based
mechanophores, we developed a new family of mechanophores based on the oxazine (OX) …
mechanophores, we developed a new family of mechanophores based on the oxazine (OX) …
Ratiometric flap** force probe that works in polymer gels
T Yamakado, S Saito - Journal of the American Chemical Society, 2022 - ACS Publications
Polymer gels have recently attracted attention for their application in flexible devices, where
mechanically robust gels are required. While there are many strategies to produce tough …
mechanically robust gels are required. While there are many strategies to produce tough …
Mechanically responsive luminescent polymers based on supramolecular cyclophane mechanophores
A new approach to cyclophane-based supramolecular mechanophores is presented. We
report a mechanically responsive cyclic motif that contains two fluorescent 1, 6-bis …
report a mechanically responsive cyclic motif that contains two fluorescent 1, 6-bis …
Rotaxane-based dual function mechanophores exhibiting reversible and irreversible responses
T Muramatsu, Y Okado, H Traeger… - Journal of the …, 2021 - ACS Publications
Mechanochromic mechanophores permit the design of polymers that indicate mechanical
events through optical signals. Here we report rotaxane-based supramolecular …
events through optical signals. Here we report rotaxane-based supramolecular …
Folded perylene diimide loops as mechanoresponsive motifs
A supramolecular mechanophore that can be integrated into polymers and indicates
deformation by a fluorescence color change is reported. Two perylene diimides (PDIs) were …
deformation by a fluorescence color change is reported. Two perylene diimides (PDIs) were …
Excited State Charge‐Transfer Complexes Enable Fluorescence Color Changes in a Supramolecular Cyclophane Mechanophore
Mechanochromic mechanophores are reporter molecules that indicate mechanical events
through changes of their photophysical properties. Supramolecular mechanophores in …
through changes of their photophysical properties. Supramolecular mechanophores in …
The Mechanochemical Synthesis and Activation of Carbon‐Rich π‐Conjugated Materials
Mechanochemistry uses mechanical force to break, form, and manipulate chemical bonds to
achieve functional transformations and syntheses. Over the last years, many innovative …
achieve functional transformations and syntheses. Over the last years, many innovative …