Mechanochemical tools for polymer materials

Y Chen, G Mellot, D van Luijk, C Creton… - Chemical Society …, 2021 - pubs.rsc.org
Mechanochemistry provides a unique approach to investigate macroscopic deformation,
failure and healing of polymer materials. The development of mechanophores–molecular …

From molecules to polymers—harnessing inter‐and intramolecular interactions to create mechanochromic materials

H Traeger, DJ Kiebala, C Weder… - Macromolecular rapid …, 2021 - Wiley Online Library
The development of mechanophores as building blocks that serve as predefined weak
linkages has enabled the creation of mechanoresponsive and mechanochromic polymer …

Azobenzene as a photoswitchable mechanophore

Y Li, B Xue, J Yang, J Jiang, J Liu, Y Zhou, J Zhang… - Nature Chemistry, 2024 - nature.com
Azobenzene has been widely explored as a photoresponsive element in materials science.
Although some studies have investigated the force-induced isomerization of azobenzene …

Fast, reversible mechanochromism of regioisomeric oxazine mechanophores: Develo** in situ responsive force probes for polymeric materials

H Qian, NS Purwanto, DG Ivanoff, AJ Halmes… - Chem, 2021 - cell.com
To address hysteretic or irreversible mechanochromism found in most bond-scission-based
mechanophores, we developed a new family of mechanophores based on the oxazine (OX) …

Ratiometric flap** force probe that works in polymer gels

T Yamakado, S Saito - Journal of the American Chemical Society, 2022 - ACS Publications
Polymer gels have recently attracted attention for their application in flexible devices, where
mechanically robust gels are required. While there are many strategies to produce tough …

Mechanically responsive luminescent polymers based on supramolecular cyclophane mechanophores

Y Sagara, H Traeger, J Li, Y Okado… - Journal of the …, 2021 - ACS Publications
A new approach to cyclophane-based supramolecular mechanophores is presented. We
report a mechanically responsive cyclic motif that contains two fluorescent 1, 6-bis …

Rotaxane-based dual function mechanophores exhibiting reversible and irreversible responses

T Muramatsu, Y Okado, H Traeger… - Journal of the …, 2021 - ACS Publications
Mechanochromic mechanophores permit the design of polymers that indicate mechanical
events through optical signals. Here we report rotaxane-based supramolecular …

Folded perylene diimide loops as mechanoresponsive motifs

H Traeger, Y Sagara, DJ Kiebala, S Schrettl… - Angewandte …, 2021 - Wiley Online Library
A supramolecular mechanophore that can be integrated into polymers and indicates
deformation by a fluorescence color change is reported. Two perylene diimides (PDIs) were …

Excited State Charge‐Transfer Complexes Enable Fluorescence Color Changes in a Supramolecular Cyclophane Mechanophore

S Thazhathethil, T Muramatsu, N Tamaoki… - Angewandte …, 2022 - Wiley Online Library
Mechanochromic mechanophores are reporter molecules that indicate mechanical events
through changes of their photophysical properties. Supramolecular mechanophores in …

The Mechanochemical Synthesis and Activation of Carbon‐Rich π‐Conjugated Materials

M Xuan, C Schumacher, C Bolm, R Göstl… - Advanced …, 2022 - Wiley Online Library
Mechanochemistry uses mechanical force to break, form, and manipulate chemical bonds to
achieve functional transformations and syntheses. Over the last years, many innovative …