Prior to the year 2000, non‐aqueous uranium chemistry mainly involved metallocene and
classical alkyl, amide, or alkoxide compounds as well as established carbene, imido, and …

Uranium complexes can be stabilized in a wide range of oxidation states, ranging from UII to
UVI and a very recent example of a UI complex. This review provides a comprehensive …

Since uranium has several common paramagnetic oxidation states, ie, 5f 1 U5+, 5f 2 U4+,
and 5f 3 U3+, one of the analytical methods commonly used for characterizing uranium …

The actinide elements are attractive alternatives to transition metals or lanthanides for the
design of exchange-coupled multinuclear single-molecule magnets. However, the synthesis …

Single-molecule magnets (SMMs) are compounds that, below a blocking temperature,
exhibit stable magnetization purely of molecular origin, and not caused by long-range …

There is a growing interest in uranium coordination chemistry, particularly as it relates to
metal–ligand multiple bonding, and in the last decade significant progress has been made …

The uranyl dication,[UO2] 2+, is the most prevalent and most thermodynamically stable form
of uranium and is a soluble and problematic environmental contaminant. It is also …

The new homoleptic ate U (III) siloxide [K (18c6)][U (OSi (O t Bu) 3) 4] 2 was prepared in
69% yield by reduction of [U (OSi (O t Bu) 3) 4] 3 with KC8. The reaction of the neutral U (III) …

The ubiquity of the cyclopentadienyl ligand permits us to use its complexes as
representative examples for the description of recent highlights in organometallic and more …

We describe the use of Cl K-edge X-ray absorption spectroscopy (XAS) and both ground-
state and time-dependent hybrid density functional theory (DFT) to probe the electronic …