Transition-metal-free C–S bond cleavage and transformation of organosulfur compounds

K Yang, Q Li, Z Li, X Sun - Chemical Communications, 2023 - pubs.rsc.org
The activation and transformation of organic chemical bonds is a fundamental scientific
problem. In the past several decades, C–S bond cleavage for the construction of C–C and C …

Dimethyl sulfoxide: yesterday's solvent, today's reagent

Z Tashrifi, MM Khanaposhtani… - Advanced Synthesis …, 2020 - Wiley Online Library
Dimethyl sulfoxide (DMSO) has had a long history of use as a polar solvent and active
pharmaceutical ingredient in the past decades. However, in this decade DMSO has attracted …

DMSO as a C1 Source for [2 + 2 + 1] Pyrazole Ring Construction via Metal-Free Annulation with Enaminones and Hydrazines

H Guo, L Tian, Y Liu, JP Wan - Organic Letters, 2021 - ACS Publications
A cascade reaction between enaminones, hydrazines, and dimethyl sulfoxide (DMSO) for
the synthesis of 1, 4-disubstituted pyrazoles catalyzed by molecular iodine in the presence …

New applications of pyridinium ylides toward heterocyclic synthesis

LD Funt, MS Novikov, AF Khlebnikov - Tetrahedron, 2020 - Elsevier
The recent advances in the syntheses of various heterocycles based on pyridinium ylides
are described. Depending on the reactivity of the pyridinium ylides and the reactants, a …

Recent advances in the use of dimethyl sulfoxide as a synthon in organic chemistry

H Lu, Z Tong, L Peng, Z Wang, SF Yin… - Topics in Current …, 2022 - Springer
Dimethyl sulfoxide (DMSO), as extremely important aprotic polar solvent and reaction
medium, has attracted widespread attention from chemists in recent years due to its wide …

Application of N, N-Dimethylethanolamine as a One-Carbon Synthon for the Synthesis of Pyrrolo [1, 2-a] quinoxalines, Quinazolin-4-ones, and Benzo [4, 5] …

M Geng, M Huang, J Kuang, W Fang… - The Journal of …, 2022 - ACS Publications
The synthesis of N-heterocycles composes a significant part of synthetic chemistry. In this
report, a Cu (II)-catalyzed green and efficient synthesis of pyrrolo [1, 2-a] quinoxaline …

The recent advances in K 2 S 2 O 8-mediated cyclization/coupling reactions via an oxidative transformation

S Kumar, K Padala - Chemical Communications, 2020 - pubs.rsc.org
Transition metal-free organic transformations using K2S2O8 is one of the most efficient
methods for the formation of carbon–carbon/carbon–heteroatom bond in organic synthesis …

Assembly of functionalized π-extended indolizine polycycles through dearomative [3+ 2] cycloaddition/oxidative decarbonylation

S **, L Wang, H Han, X Liu, Z Bu… - Chemical …, 2021 - pubs.rsc.org
Reported herein is an unexpected construction of functionalized π-extended indolizine
polycycles through a one-pot two-step cascade process comprising the base-promoted …

DMSO as a Methine Source in TFA-Mediated One-Pot Tandem Regioselective Synthesis of 3-Substituted-1-Aryl-1H-Pyrazolo-[3,4-b]quinolines from Anilines and …

P Yadav, A Awasthi, S Gokulnath… - The Journal of Organic …, 2021 - ACS Publications
An acid-mediated and DMSO participant one-pot tandem synthesis of 3-substituted-1-aryl-1
H-pyrazolo-[3, 4-b] quinoline from readily available anilines and pyrazolones was achieved …

Research progress of self-organized reaction networks for cascade reactions

YX Tang, AX Wu - Tetrahedron, 2024 - Elsevier
The concept of “reaction network” represents a system that is constructed from reactions
between different organic units basing on logical transformation relationships. This network …