Recent advances in quantum scattering calculations on polyatomic bimolecular reactions

B Fu, X Shan, DH Zhang, DC Clary - Chemical Society Reviews, 2017 - pubs.rsc.org
This review surveys quantum scattering calculations on chemical reactions of polyatomic
molecules in the gas phase published in the last ten years. These calculations are useful …

State-to-State Dynamics in Mode-Selective Polyatomic Reactions

H Pan, B Zhao, H Guo, K Liu - The Journal of Physical Chemistry …, 2023 - ACS Publications
Chemical reactions are intrinsically quantum mechanical transformations of reactants to
products. Recent experimental and theoretical advances have enabled the exploration of …

Advances and new challenges to bimolecular reaction dynamics theory

J Li, B Zhao, D **e, H Guo - The Journal of Physical Chemistry …, 2020 - ACS Publications
Dynamics of bimolecular reactions in the gas phase are of foundational importance in
combustion, atmospheric chemistry, interstellar chemistry, and plasma chemistry. These …

Full-dimensional quantum dynamics calculations for H+ CHD3→ H2+ CD3: The effect of multiple vibrational excitations

R Ellerbrock, U Manthe - The Journal of Chemical Physics, 2018 - pubs.aip.org
Initial state-selected reaction probabilities for the H+ CHD 3→ H 2+ CD 3 reaction starting
from various different ro-vibrational states of CHD 3 are studied by accurate full-dimensional …

State‐to‐state quantum reactive scattering in four‐atom systems

B Zhao, H Guo - Wiley Interdisciplinary Reviews: Computational …, 2017 - Wiley Online Library
The recent advances in quantum mechanical studies of four‐atom reactions at the state‐to‐
state level are reviewed. With six internal degrees of freedom, such reactions offer richer …

Natural reaction channels in H+ CHD 3→ H 2+ CD 3

R Ellerbrock, U Mantheuwe - Faraday Discussions, 2018 - pubs.rsc.org
Natural reaction channels are defined by the singular value decomposition of the S-matrix
and can be interpreted as pathways through the transition state of the reaction. Here, the …

H+ CH4→ H2+ CH3 initial state-selected reaction probabilities on different potential energy surfaces

R Ellerbrock, U Manthe - Chemical Physics, 2017 - Elsevier
Initial state-selected reaction probabilities for the H+ CH 4→ H 2+ CH 3 reaction on a
recently developed potential energy surface which employs neutral network fitting based on …

[HTML][HTML] A reactant-coordinate-based approach to state-to-state differential cross sections for tetratomic reactions

B Zhao, Z Sun, H Guo - The Journal of Chemical Physics, 2016 - pubs.aip.org
A new algorithm is proposed to compute quantum mechanically state-to-state differential
cross sections for reactions involving four atoms in full dimensionality. This algorithm, which …

[HTML][HTML] State-to-state differential cross sections for D2+ OH→ D+ DOH reaction: Influence of vibrational excitation of OH reactant

B Zhao, Z Sun, H Guo - The Journal of chemical physics, 2016 - pubs.aip.org
State-to-state differential cross sections (DCSs) are computed quantum mechanically in full
dimensionality for the title reaction using a reactant-product decoupling scheme. The DCSs …

Smolyak representations with absorbing boundary conditions for reaction path Hamiltonian model of reactive scattering

L Dupuy, D Lauvergnat, Y Scribano - Chemical Physics Letters, 2022 - Elsevier
In this work, we present the efficient combination of Smolyak representations with time
independent quantum mechanical approach using absorbing boundary conditions for the …