Advances and opportunities in the exciting world of azobenzenes

FA Jerca, VV Jerca, R Hoogenboom - Nature Reviews Chemistry, 2022 - nature.com
Azobenzenes are archetypal molecules that have a central role in fundamental and applied
research. Over the course of almost two centuries, the area of azobenzenes has witnessed …

Advances in application of azobenzene as a trigger in biomedicine: molecular design and spontaneous assembly

HB Cheng, S Zhang, J Qi, XJ Liang… - Advanced …, 2021 - Wiley Online Library
Azobenzene is a well‐known derivative of stimulus‐responsive molecular switches and has
shown superior performance as a functional material in biomedical applications. The results …

Step** out of the blue: from visible to near‐IR triggered photoswitches

Z Zhang, W Wang, M O'Hagan, J Dai… - Angewandte Chemie …, 2022 - Wiley Online Library
Light offers unique opportunities for controlling the activity of materials and biosystems with
high spatiotemporal resolution. Molecular photoswitches are chromophores that undergo …

In Vivo Photopharmacology

K Hull, J Morstein, D Trauner - Chemical reviews, 2018 - ACS Publications
Synthetic photoswitches have been known for many years, but their usefulness in biology,
pharmacology, and medicine has only recently been systematically explored. Over the past …

On the promise of photopharmacology using photoswitches: a medicinal chemist's perspective

MJ Fuchter - Journal of Medicinal Chemistry, 2020 - ACS Publications
Photopharmacology is a growing area of endeavor that employs photoswitchable ligands to
allow for light-dependent pharmacological activity. By coupling light to therapeutic action …

Azobenzene-based solar thermal fuels: design, properties, and applications

L Dong, Y Feng, L Wang, W Feng - Chemical Society Reviews, 2018 - pubs.rsc.org
Development of renewable energy technologies has been a significant area of research
amongst scientists with the aim of attaining a sustainable world society. Solar thermal fuels …

Phenylazothiazoles as visible-light photoswitches

R Lin, PK Hashim, S Sahu, AS Amrutha… - Journal of the …, 2023 - ACS Publications
A novel class of photoswitches based on a phenylazothiazole scaffold that undergoes
reversible isomerization under visible-light irradiation is reported. The photoswitch, which …

Recent implementations of molecular photoswitches into smart materials and biological systems

ZL Pianowski - Chemistry–A European Journal, 2019 - Wiley Online Library
Light is a nearly ideal stimulus for molecular systems. It delivers information encoded in the
form of wavelengths and their intensities with high precision in space and time. Light is a …

Reversible spatiotemporal control of induced protein degradation by bistable PhotoPROTACs

P Pfaff, KTG Samarasinghe, CM Crews… - ACS Central …, 2019 - ACS Publications
Off-tissue effects are persistent issues of modern inhibition-based therapies. By merging the
strategies of photopharmacology and small-molecule degraders, we introduce a novel …

Photoinduced reversible solid‐to‐liquid transitions for photoswitchable materials

WC Xu, S Sun, S Wu - Angewandte Chemie International …, 2019 - Wiley Online Library
Heating and cooling can induce reversible solid‐to‐liquid transitions of matter. In contrast,
athermal photochemical processes can induce reversible solid‐to‐liquid transitions of some …