Reactivity by Design Metallaoxetanes as Centerpieces in Reaction Development
A Dauth, JA Love - Chemical Reviews, 2011 - ACS Publications
The development of new catalytic reactions that perform chemical transformations with high
selectivity and efficiency is a key goal in chemical research. Many new reactions are …
selectivity and efficiency is a key goal in chemical research. Many new reactions are …
Reactivity and regioselectivity of insertion of unsaturated molecules into M− C (M= Ir, Rh) bonds of cyclometalated complexes
The reactivity of four different cyclometalated iridium and rhodium complexes (1, Ir− N− Me;
2, Rh− N− Me; 3, Ir− N− Py; 4, Rh− N− Py) with ancillary ligands with different electronic and …
2, Rh− N− Me; 3, Ir− N− Py; 4, Rh− N− Py) with ancillary ligands with different electronic and …
Nine-membered osmacycles derived from metathesis reactions between Alkynes and an osmafuran
Y Lin, L Gong, H Xu, X He, TB Wen, H **a - Organometallics, 2009 - ACS Publications
Ring-expansion reactions of the five-membered osmafuran Os { CHC (PPh3) C (O) OEt}
Cl2 (PPh3) 2 (1) via alkyne insertion have been investigated, which lead to the formation of …
Cl2 (PPh3) 2 (1) via alkyne insertion have been investigated, which lead to the formation of …
Photocleavage of coordinated NO under visible light from two different classes of organometallic ruthenium nitrosyl complexes: reversible binding of phenolato …
The structurally similar Ru (III) complexes [Ru (LSB1)(PPh3) 2Cl](1), where LSB1H2= 2-(4-
chlorobenzylidineamino) phenol and H= dissociable protons, and [Ru (LAZ1)(PPh3) 2Cl](2) …
chlorobenzylidineamino) phenol and H= dissociable protons, and [Ru (LAZ1)(PPh3) 2Cl](2) …
Phenolato and alkoxo promoted change in the ligand coordination mode in a four-membered ortho-metalated ruthenium (II) organometallics
MK Ghosh, J Chowdhury, P Garu, A Mondal… - Polyhedron, 2025 - Elsevier
The reaction of Ru (κ 2 C, O-RL)(PPh 3) 2 (CO)(Cl)[κ 2 C, O-RL is C 6 H 2 O-2-CHNHC 6 H 4
R (p)-3-Me-5 and R= Me, OMe, Cl] with excess sodium p-methylphenolate (p-MeC 6 H 4 …
R (p)-3-Me-5 and R= Me, OMe, Cl] with excess sodium p-methylphenolate (p-MeC 6 H 4 …
Isonitrile Insertion into the Ru− O Bond and Migratory C− C Bond Formation. Novel Organoruthenium Imidic Ester and Acyl Species
Organometallics of type [Ru (C6H2O-2-CHNHC6H4R-3-Me-5)(PPh3) 2 (CO)(Cl)], 3 (R= H,
Me, OMe, Cl), incorporating a four-membered C, O chelate ring smoothly react with CNBut in …
Me, OMe, Cl), incorporating a four-membered C, O chelate ring smoothly react with CNBut in …
Reactions of a Trinuclear Ruthenium Complex Derived from 3-(2-Pyridyl) indene with Diphenylacetylene and Phenylacetylene: Insertion of Alkynes into the Ru− C …
D Chen, C Zhang, S Xu, H Song, B Wang - Organometallics, 2011 - ACS Publications
Thermal treatment of the trinuclear ruthenium complex {μ2-η5: η1-(C5H4N)(C9H5)} Ru3
(CO) 9 (1) with 1 equiv of diphenylacetylene gave the trinuclear complex {μ3-η1: η2: η5 …
(CO) 9 (1) with 1 equiv of diphenylacetylene gave the trinuclear complex {μ3-η1: η2: η5 …
Synthesis and structure of pyridine-2-thiolato ruthenium aryls bearing a pendant imine–phenol function
The reaction of Ru (η2-RL)(PPh3) 2 (CO) Cl (1) with sodium pyridine-2-thiolate (Napyt) has
afforded the complexes of the type Ru (η1-RL)(PPh3) 2 (CO)(pyt)(3) in excellent yield (η2 …
afforded the complexes of the type Ru (η1-RL)(PPh3) 2 (CO)(pyt)(3) in excellent yield (η2 …
Carbonylation of four-membered ruthenium and osmium metallacycles incorporating an orthometallated phenolic function: New acylruthenium and arylosmium …
BK Panda, A Chakravorty - Journal of organometallic chemistry, 2005 - Elsevier
The solution reaction of Ru (QL1)(PPh3) 2 (CO) Cl (3) and Os (QL1)(PPh3) 2 (CO) Br (4)
with carbon monoxide at one atmosphere pressure has respectively afforded the orange …
with carbon monoxide at one atmosphere pressure has respectively afforded the orange …
Synthesis, Structure, and Properties of Biimidazole‐Chelated Arylruthenium Complexes
BK Panda, S Sengupta… - European Journal of …, 2004 - Wiley Online Library
By reacting Ru (η2‐RL)(PPh3) 2 (CO) Cl (1) with excess 4, 5‐dimethyl‐2, 2′‐biimidazole
(dmbi), organometallics of the type [Ru (η1‐RL)(PPh3) 2 (CO)(dmbi)](PF6)(2) have been …
(dmbi), organometallics of the type [Ru (η1‐RL)(PPh3) 2 (CO)(dmbi)](PF6)(2) have been …