N-heterocyclic carbene coordinated metal nanoparticles and nanoclusters
N-heterocyclic carbenes (NHCs) represent one of the most important organic ligands in
coordination chemistry, and have been recently attracting increasing attention in …
coordination chemistry, and have been recently attracting increasing attention in …
Fundamentals and applications of N-heterocyclic carbene functionalized gold surfaces and nanoparticles
The discovery of N-heterocyclic carbenes (NHCs) revolutionized organometallic chemistry
due to their strong metal–ligand bonds. These strong bonds also lend enhanced stability to …
due to their strong metal–ligand bonds. These strong bonds also lend enhanced stability to …
When design meets function: the prodigious role of surface ligands in regulating nanoparticle chemistry
The underlying power of “interplay of forces” in controlling the properties and functions at the
nanoscale is highlighted in this perspective. This interplay is achieved by installing attractive …
nanoscale is highlighted in this perspective. This interplay is achieved by installing attractive …
Probing Protein Corona Formation around Gold Nanoparticles: Effects of Surface Coating
There has been much interest in integrating various inorganic nanoparticles (nanoscale
colloids) in biology and medicine. However, buildup of a protein corona around the …
colloids) in biology and medicine. However, buildup of a protein corona around the …
Using Surface-Enhanced Raman Spectroscopy to Unravel the Wingtip-Dependent Orientation of N-Heterocyclic Carbenes on Gold Nanoparticles
N-Heterocyclic carbenes (NHCs) are an attractive alternative to thiol ligands when forming
self-assembled monolayers on noble-metal surfaces; however, relative to the well-studied …
self-assembled monolayers on noble-metal surfaces; however, relative to the well-studied …
Robust Water-Soluble Gold Nanoparticles via Polymerized Mesoionic N-Heterocyclic Carbene–Gold(I) Complexes
DTH Nguyen, M Bélanger-Bouliga, LR Shultz… - Chemistry of …, 2021 - ACS Publications
Gold nanomaterials have widespread applications across multiple areas of science and
technology. Sulfur-containing ligands (thiols and thioethers) have been traditionally used as …
technology. Sulfur-containing ligands (thiols and thioethers) have been traditionally used as …
Ad aurum: tunable transfer of N-heterocyclic carbene complexes to gold surfaces
NL Dominique, R Chen, AVB Santos… - Inorganic Chemistry …, 2022 - pubs.rsc.org
The exceptional stability of N-heterocyclic carbene (NHC) monolayers on gold surfaces and
nanoparticles (AuNPs) is enabling new and diverse applications from catalysis to …
nanoparticles (AuNPs) is enabling new and diverse applications from catalysis to …
Polymer N-Heterocyclic Carbene (NHC) Ligands for Silver Nanoparticles
Polymer N-heterocyclic carbenes (NHCs) are a class of robust surface ligands to provide
superior colloidal stability for metal nanoparticles (NPs) under various harsh conditions. We …
superior colloidal stability for metal nanoparticles (NPs) under various harsh conditions. We …
Thermodynamics of nanocrystal–ligand binding through isothermal titration calorimetry
AB Greytak, SL Abiodun, JM Burrell, EN Cook… - Chemical …, 2022 - pubs.rsc.org
Manipulations of nanocrystal (NC) surfaces have propelled the applications of colloidal NCs
across various fields such as bioimaging, catalysis, electronics, and sensing applications. In …
across various fields such as bioimaging, catalysis, electronics, and sensing applications. In …
Beyond the Gold–Thiol Paradigm: Exploring Alternative Interfaces for Electrochemical Nucleic Acid-Based Sensing
N Arroyo-Currás - ACS sensors, 2024 - ACS Publications
Nucleic acid-based electrochemical sensors (NBEs) use oligonucleotides as affinity
reagents for the detection of a variety of targets, ranging from small-molecule therapeutics to …
reagents for the detection of a variety of targets, ranging from small-molecule therapeutics to …