Constitutional Dynamic Materials Toward Natural Selection of Function
Y Zhang, M Barboiu - Chemical Reviews, 2016 - ACS Publications
Constitutional dynamic chemistry (CDC) 1− 7 and its application, Dynamic combinatorial
chemistry (DCC), 8− 18 are emergent approaches to generate chemical diversity. In contrast …
chemistry (DCC), 8− 18 are emergent approaches to generate chemical diversity. In contrast …
Encapsulation versus Self-Aggregation toward Highly Selective Artificial K+ Channels
M Barboiu - Accounts of Chemical Research, 2018 - ACS Publications
Conspectus Natural ion-channel proteins allow ion transport across cell membranes at rates
very close to those for ionic diffusion in water. Among them, natural KcsA K+ channels …
very close to those for ionic diffusion in water. Among them, natural KcsA K+ channels …
Oriented chiral water wires in artificial transmembrane channels
Aquaporins (AQPs) feature highly selective water transport through cell membranes, where
the dipolar orientation of structured water wires spanning the AQP pore is of considerable …
the dipolar orientation of structured water wires spanning the AQP pore is of considerable …
Imino-chitosan biodynamers
The imine-bond formation on chitosan backbones occurs with very low yields in aqueous
solutions and is significantly improved in hydrogels or in solid state films. The dynamic …
solutions and is significantly improved in hydrogels or in solid state films. The dynamic …
Out‐of‐water constitutional self‐organization of chitosan–cinnamaldehyde dynagels
An investigation of the constitutional adaptive gelation process of chitosan/cinnamaldehyde
(C/Cy) dynagels is reported. These gels generate timely variant macroscopic organization …
(C/Cy) dynagels is reported. These gels generate timely variant macroscopic organization …
Antifungal vanillin–imino-chitosan biodynameric films
Vanillin–chitosan biodynamers have been prepared and structure–morphology correlations
revealed the pathway of progressive incorporation of the aldehyde onto chitosan …
revealed the pathway of progressive incorporation of the aldehyde onto chitosan …
Ordered hybrids from template‐free organosilane self‐assembly
A Chemtob, L Ni, C Croutxé‐Barghorn… - … –A European Journal, 2014 - Wiley Online Library
Despite considerable achievements over the last two decades, nonporous organic–
inorganic hybrid materials are mostly amorphous, especially in the absence of solvothermal …
inorganic hybrid materials are mostly amorphous, especially in the absence of solvothermal …
Dynamic hybrid materials for constitutional self-instructed membranes
Constitutional self-instructed membranes were developed and used for mimicking the
adaptive structural functionality of natural ion-channel systems. These membranes are …
adaptive structural functionality of natural ion-channel systems. These membranes are …
Dynamic interactive systems: dynamic selection in hybrid organic–inorganic constitutional networks
M Barboiu - Chemical Communications, 2010 - pubs.rsc.org
Dynamic interactive systems are defined by networks of exchanging and reversibly
connected objects (supermolecules, polymers, biomolecules, biopolymers, pores …
connected objects (supermolecules, polymers, biomolecules, biopolymers, pores …
Self-organized proton conductive layers in hybrid proton exchange membranes, exhibiting high ionic conductivity
M Michau, M Barboiu - Journal of Materials Chemistry, 2009 - pubs.rsc.org
We describe a proton exchange membrane (PEM) system in which the self-organization of
molecular precursors generates directional proton layers of high ionic group content in a …
molecular precursors generates directional proton layers of high ionic group content in a …