Transition-metal chemistry of the heavier alkaline earth atoms Ca, Sr, and Ba

M Zhou, G Frenking - Accounts of Chemical Research, 2021 - ACS Publications
Conspectus Alkaline earth elements beryllium, magnesium, calcium, strontium, and barium
with an n s2 valence-shell configuration are usually classified as main-group elements that …

Off the Beaten Track—A Hitchhiker's Guide to Beryllium Chemistry

D Naglav, MR Buchner, G Bendt… - Angewandte Chemie …, 2016 - Wiley Online Library
This Minireview aims to give an introduction to beryllium chemistry for all less‐experienced
scientists in this field of research. Up to date information on the toxicity of beryllium and its …

A neutral beryllium (I) radical

C Czernetzki, M Arrowsmith, F Fantuzzi… - Angewandte Chemie …, 2021 - Wiley Online Library
A Neutral Beryllium(I) Radical - Czernetzki - 2021 - Angewandte Chemie International Edition -
Wiley Online Library Skip to Article Content Skip to Article Information Wiley Online Library …

Advances in beryllium coordination chemistry

LC Perera, O Raymond, W Henderson… - Coordination Chemistry …, 2017 - Elsevier
Beryllium has a unique combination of properties which has made it a vital component in a
wide range of technical sectors and consumer industries. However, beryllium is extremely …

Recent contributions to the coordination chemistry of beryllium

MR Buchner - Chemistry–A European Journal, 2019 - Wiley Online Library
Given the alleged extreme toxicity of beryllium and its compounds, it is the least investigated
nonradioactive element. However, beryllium exhibits unique properties among the elements …

Unusually Short Be−Be Distances with and without a Bond in Be2F2 and in the Molecular Discuses Be2B8 and Be2B7

Z Cui, W Yang, L Zhao, Y Ding… - Angewandte Chemie, 2016 - Wiley Online Library
Quantum‐chemical calculations at the CCSD (T)/cc‐pVTZ level of theory show that beryllium
subfluoride, Be2F2, has a bond dissociation energy of De= 76.9 kcal mol− 1, which sets a …

Synthesis, Structural Characterization, and bonding of molecular heavier beryllium chalcogenides

C Czernetzki, T Tröster, L Endres… - … A European Journal, 2023 - Wiley Online Library
The reactions of a cyclic alkyl (amino) carbene (CAAC)‐stabilized beryllium radical with
E2Ph2 (E= S, Se, Te) and of a beryllole with HEPh (E= S, Se) yield the corresponding …

π Back-Donation from a Beryllium Dibromide Fragment at the Expense of Its σ Strength

LR Thomas-Hargreaves, S Pan, SI Ivlev… - Inorganic …, 2021 - ACS Publications
It is common knowledge that metal-to-ligand π back-donation requires filled atomic orbitals
at the metal center. However, we show through a combined experimental and theoretical …

Recent progress in beryllium organometallic chemistry

D Parveen, RK Yadav, DK Roy - Chemical Communications, 2024 - pubs.rsc.org
Beryllium possesses a unique amalgamation of characteristics, its electronegativity
included, that not only make it a vital component in a wide range of technical sectors and …

Highly Coordinated Heteronuclear Calcium–Iron Carbonyl Cation Complexes [CaFe(CO)n]+ (n=5–12) with d−d Bonding

X **, Y Bai, Y Zhou, G Wang, L Zhao… - Angewandte Chemie …, 2021 - Wiley Online Library
Heteronuclear calcium–iron carbonyl cation complexes in the form of [CaFe (CO) n]+(n= 5–
12) are produced in the gas phase. Infrared photodissociation spectroscopy in conjunction …