Carbon–Carbon Bond Cleavage for Late-Stage Functionalization

YF Liang, M Bilal, LY Tang, TZ Wang, YQ Guan… - Chemical …, 2023 - ACS Publications
Late-stage functionalization (LSF) introduces functional group or structural modification at
the final stage of the synthesis of natural products, drugs, and complex compounds. It is …

Palladium‐Catalyzed Enantio‐and Regioselective Ring‐Opening Hydrophosphinylation of Methylenecyclopropanes

J Zhou, L Meng, S Lin, B Cai… - Angewandte Chemie …, 2023 - Wiley Online Library
Transition metal‐catalyzed hydrofunctionalization of methylenecyclopropanes (MCPs) has
presented a considerable challenge due to the difficult manipulation of regioselectivity and …

Recent Developments of Palladium-and Rhodium-Catalyzed β-Carbon Elimination Strategies

AD Marchese, B Mirabi, M Lautens - Synthesis, 2023 - thieme-connect.com
The activation of C–C bonds via transition metal catalysis has become an increasingly
popular strategy in organic synthesis. An emerging method to cleave C–C bonds is to …

Rh (III)-Catalyzed Dienylation and Cyclopropylation of 1, 2, 3-Benzotriazinones with Alkylidenecyclopropanes

YZ Liu, YF Zeng, J Wei, L **ao, B Shu, JL Song… - Organic …, 2023 - ACS Publications
Rh (III)-catalyzed dienylation and cyclopropylation of 1, 2, 3-benzotriazinones with
alkylidenecyclopropanes (ACPs) has been achieved. Different from the previous reports of …

The synthesis of spirocyclopropane skeletons enabled by Rh (III)-catalyzed enantioselective C–H activation/[4+ 2] annulation

H Wang, Y Li, L Huang, H Xu, Y Jiao, Z Zhou, Z Tang… - Chem Catalysis, 2023 - cell.com
Considering the prevalence of spirocyclopropane motifs in bioactive compounds, the
development of efficient methods for the synthesis of various chiral spirocyclopropane motifs …

Ru(II)- or Rh(III)-Catalyzed Annulation of Aromatic/Vinylic Acids with Alkylidenecyclopropanes via C–H Activation

B Ramesh, M Jeganmohan - The Journal of Organic Chemistry, 2022 - ACS Publications
An efficient and new route for the synthesis of (E)-4-benzylideneisochroman-1-ones through
tandem cascade annulation of benzoic acids with alkylidenecyclopropanes using Ru (II) as …

Synthesis of 3, 4, 5-trisubstituted phenols via Rh (III)-catalyzed alkenyl C–H activation assisted by phosphonium cations

Y Mao, W Chen, C Li, L Miao, Y Lin, F Ling… - Chemical …, 2023 - pubs.rsc.org
An efficient method for the construction of various 3, 4, 5-trisubstituted phenol derivatives
has been achieved via the Rh (III)-catalyzed coupling of phosphonium cations with internal …

Rh (iii)-Catalyzed dienylation and cyclopropylation of indoles at the C4 position with alkylidenecyclopropanes

YZ Liu, YF Zeng, B Shu, YC Zheng, L **ao… - Organic Chemistry …, 2022 - pubs.rsc.org
Herein, we report a Rh (III)-catalyzed C–H functionalization of indoles at the C4 position with
alkylidenecyclopropanes (ACPs). Motifs of dienes or cyclopropanes could be selectively …

Development of novel transition metal-catalyzed synthetic approaches for the synthesis of a dihydrobenzofuran nucleus: a review

R Ashraf, AF Zahoor, KG Ali, U Nazeer, MJ Saif… - RSC …, 2024 - pubs.rsc.org
The synthesis of dihydrobenzofuran scaffolds bears pivotal significance in the field of
medicinal chemistry and organic synthesis. These heterocyclic scaffolds hold immense …

Stereoselective Three‐Component Construction of Conjugated 1,3‐Dienes via Palladium‐Catalyzed Alkene/Allene/Carbenoid Insertion Cascade

H Zhao, Y Jiang, T Weng, Y Shang… - Advanced Synthesis & …, 2023 - Wiley Online Library
A three component construction of conjugated 1, 3‐dienes bearing oxindoles or
isoquinolinediones from alkenylated aryl iodides, allenes and diazo compounds via a …