Molecular cavity for catalysis and formation of metal nanoparticles for use in catalysis

R Saha, B Mondal, PS Mukherjee - Chemical Reviews, 2022 - ACS Publications
The employment of weak intermolecular interactions in supramolecular chemistry offers an
alternative approach to project artificial chemical environments like the active sites of …

Design and applications of water-soluble coordination cages

EG Percástegui, TK Ronson, JR Nitschke - Chemical Reviews, 2020 - ACS Publications
Compartmentalization of the aqueous space within a cell is necessary for life. In similar
fashion to the nanometer-scale compartments in living systems, synthetic water-soluble …

Metal–organic cages for molecular separations

D Zhang, TK Ronson, YQ Zou, JR Nitschke - Nature Reviews Chemistry, 2021 - nature.com
Separation technology is central to industries as diverse as petroleum, pharmaceuticals,
mining and life sciences. Metal–organic cages, a class of molecular containers formed via …

Switchable metallacycles and metallacages

HY Lin, YT Wang, X Shi, HB Yang, L Xu - Chemical Society Reviews, 2023 - pubs.rsc.org
Two-dimensional metallacycles and three-dimensional metallacages constructed by
coordination-driven self-assembly have attracted much attention because they exhibit …

Recent developments in the construction and applications of platinum-based metallacycles and metallacages via coordination

Y Sun, C Chen, J Liu, PJ Stang - Chemical Society Reviews, 2020 - pubs.rsc.org
Coordination-driven suprastructures have attracted much interest due to their unique
properties. Among these structures, platinum-based architectures have been broadly …

Transformation networks of metal–organic cages controlled by chemical stimuli

E Benchimol, BNT Nguyen, TK Ronson… - Chemical Society …, 2022 - pubs.rsc.org
The flexibility of biomolecules enables them to adapt and transform as a result of signals
received from the external environment, expressing different functions in different contexts …

Picking the lock of coordination cage catalysis

TK Piskorz, V Martí-Centelles, RL Spicer, F Duarte… - Chemical …, 2023 - pubs.rsc.org
The design principles of metallo-organic assembly reactions have facilitated access to
hundreds of coordination cages of varying size and shape. Many of these assemblies …

Biomedically relevant self-assembled metallacycles and metallacages

H Sepehrpour, W Fu, Y Sun… - Journal of the American …, 2019 - ACS Publications
Diverse metal–organic complexes (MOCs), shaped as rectangles, triangles, hexagons,
prisms, and cages, can be formed by coordination between metal ions (Pt, Pd, Ru, Rh, Ir, Zn …

Guest-driven self-assembly and chiral induction of photofunctional lanthanide tetrahedral cages

SJ Hu, XQ Guo, LP Zhou, DN Yan… - Journal of the …, 2022 - ACS Publications
Chiral luminescent lanthanide–organic cages have many potential applications in
enantioselective recognition, sensing, and asymmetric catalysis. However, due to the …

Supramolecular fluorescent sensors: An historical overview and update

C Guo, AC Sedgwick, T Hirao, JL Sessler - Coordination chemistry reviews, 2021 - Elsevier
Since as early as 1867, molecular sensors have been recognized as being intelligent
“devices” capable of addressing a variety of issues related to our environment and health …