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To each his own: isonitriles for all flavors. Functionalized isocyanides as valuable tools in organic synthesis
M Giustiniano, A Basso, V Mercalli… - Chemical Society …, 2017 - pubs.rsc.org
The term functionalized isocyanides refers to all those isocyanides in which a neighbouring
functional group can finely tune the reactivity of the isocyano group or can be exploited in …
functional group can finely tune the reactivity of the isocyano group or can be exploited in …
One Reacts as Two: Applications of N-Isocyaniminotriphenylphosphorane in Diversity-Oriented Synthesis
N-Isocyaniminotriphenylphosphorane (NIITP) is a functionalized isonitrile that has been
extensively applied in a variety of organic reactions during the last two decades. This …
extensively applied in a variety of organic reactions during the last two decades. This …
Silver-Mediated [3 + 2] Cycloaddition of Alkynes and N-Isocyanoiminotriphenylphosphorane: Access to Monosubstituted Pyrazoles
F Yi, W Zhao, Z Wang, X Bi - Organic Letters, 2019 - ACS Publications
A silver-mediated [3+ 2] cycloaddition of “CNN” and “C≡ C” for constructing pyrazoles has
been described. The “CNN” building block used is N-isocyanoiminotriphenylphosphorane …
been described. The “CNN” building block used is N-isocyanoiminotriphenylphosphorane …
A Cobalt Mediated Nitrene Transfer aza-Wittig Cascade Reaction To Access 1,3,4-Oxadiazole Scaffolds
A cobalt (II) mediated three-component synthesis of 5-substituted-N-sulfonyl-1, 3, 4-
oxadiazol-2 (3 H)-imines using sulfonyl azides, N-isocyaniminotriphenylphosphorane …
oxadiazol-2 (3 H)-imines using sulfonyl azides, N-isocyaniminotriphenylphosphorane …
Silver-Mediated Direct C–H Cyanation of Terminal Alkynes with N-Isocyanoiminotriphenylphosphorane
H Wang, P Mi, W Zhao, R Kumar, X Bi - Organic Letters, 2017 - ACS Publications
A direct cyanation of terminal alkynes for the synthesis of propionitrile derivatives, with the
aid of silver salt using water additive, has been achieved. The cyano source used is N …
aid of silver salt using water additive, has been achieved. The cyano source used is N …
Synthesis, carbonic anhydrase inhibition, anticancer activity, and molecular docking studies of 1, 3, 4-oxadiazole derivatives
In this work, we have synthesized various organic compounds possessing 1, 3, 4-oxadiazole
as a core structure and the structure of the newly synthesized target compounds has been …
as a core structure and the structure of the newly synthesized target compounds has been …
Preparation of fully substituted 1, 3, 4-oxadiazole derivatives from N-isocyaniminotriphenylphosphorane,(E)-cinnamic acids, chloroacetone and primary amines
A Ramazani, FZ Nasrabadi, Z Karimi… - Bulletin of the Korean …, 2011 - koreascience.kr
The 1: 1 imine intermediate generated by the addition of primary amine to chloroacetone is
trapped by N-isocyaniminotriphenylphosphorane in the presence of (E)-cinnamic acids and …
trapped by N-isocyaniminotriphenylphosphorane in the presence of (E)-cinnamic acids and …
Reactivity of N-(isocyanoimino) triphenylphosphorane toward group 13 Lewis acids
B Tang, S Ju, W Yan, T Chen, DW Stephan… - Chemical …, 2024 - pubs.rsc.org
The species Ph3PNNC 1 reacts with the group 13 Lewis acids E (C6F5) 3 (E= B or Al), HB
(C6F5) 2, ClAl (C6F5) 2 and ECl3 (E= Ga or In) to give the Lewis acid–base adduct …
(C6F5) 2, ClAl (C6F5) 2 and ECl3 (E= Ga or In) to give the Lewis acid–base adduct …
Progress in Reactions of N‐Isocyanoiminotriphenylphosphorane
Y Wang, C Zhang - ChemistrySelect, 2020 - Wiley Online Library
N‐isocyanoiminotriphenylphosphorane has been widely applied in diverse organic
synthesis due to the favorable structure of isocyano neighbouring iminophosphorane. In this …
synthesis due to the favorable structure of isocyano neighbouring iminophosphorane. In this …
Synthesis of 1,3,4-oxadiazoles from the reaction of N-isocyaniminotriphenylphosphorane (NICITPP) with cyclohexanone, a primary amine and an aromatic carboxylic acid via …
The 1: 1 imine intermediate generated by the addition of a primary amine to cyclohexanone
trapped by N-isocyaniminotriphenylphosphorane (NICITPP) in the presence of aromatic …
trapped by N-isocyaniminotriphenylphosphorane (NICITPP) in the presence of aromatic …