Metal ions play significant roles in numerous fields including chemistry, geochemistry,
biochemistry, and materials science. With computational tools increasingly becoming …

Abstract Two-dimensional (2D) transition-metal carbides and nitrides (MXenes) combine the
electronic and mechanical properties of 2D inorganic crystals with chemically modifiable …

In the present study, we successfully synthesized N-doped carbon quantum dots (N-CQDs)
using a top-down approach, ie, hydroxyl radical opening of fullerene with hydrogen …

Abstract Although CrO x/Al 2 O 3 has been widely applied for light alkanes dehydrogenation,
there is insufficient understanding on the dehydrogenation of long-chain alkanes that no …

Catalysis by high-valent metals such as titanium (iv) impacts our lives daily through
reactions like olefin polymerization. In any catalysis, optimization involves a careful choice of …

Oxidation of a series of CrV nitride salen complexes (Cr V NSal R) with different para-
phenolate substituents (R= CF3, tBu, NMe2) was investigated to determine how the locus of …

A rare Ta bis (imido) complex, which has unique reactivity, was prepared by manipulating
the coordination sphere of a CCC-NHC pincer Ta complex. The reaction of lithium tert …

Two lanthanide–organic frameworks [Ln (HPIDC)(m-bdc)· 1.5 H2O] n (Ln= Eu 1 or Tb 2;
H3PIDC= 2-(4-pyridyl)-1H-imidazole-4, 5-dicarboxylic acid; m-H2bdc= 1, 3 …

We describe the synthesis of the linear N-heterocyclic carbene (NHC)-based chromium (I)
silylamide [(IMes) Cr (N {Dipp} Si i Pr3)](IMes= 1, 3-dimesityl-imidazol-2-ylidene, Dipp= 2, 6 …

Multiple distinct oxidative group transfer reactions to low valent chromium were examined.
Six new chromium complexes were prepared from a highly electronically unsaturated Cr (II) …