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Copolymerization of carbon dioxide and epoxides by metal coordination complexes
The catalytic copolymerization of CO 2 with epoxides to give polycarbonates was discovered
nearly 50 years ago. The last 10 years have been particularly exciting for the development …
nearly 50 years ago. The last 10 years have been particularly exciting for the development …
Update and challenges in carbon dioxide‐based polycarbonate synthesis
The utilization of carbon dioxide as a comonomer to produce polycarbonates has attracted a
great deal of attention from both industrial and academic communities because it promises …
great deal of attention from both industrial and academic communities because it promises …
Intricacies of Cation–Anion Combinations in Imidazolium Salt-Catalyzed Cycloaddition of CO2 Into Epoxides
The cycloaddition of CO2 into epoxides catalyzed by imidazolium and related salts
continues to attract attention due to the industrial importance of the cyclic carbonate …
continues to attract attention due to the industrial importance of the cyclic carbonate …
Green polycarbonates prepared by the copolymerization of CO2 with epoxides
Polycarbonates can be prepared by the copolymerization of epoxides with carbon dioxide
as an inexpensive, abundant, nontoxic, and renewable feedstock. This review covers the …
as an inexpensive, abundant, nontoxic, and renewable feedstock. This review covers the …
Superbase/cellulose: an environmentally benign catalyst for chemical fixation of carbon dioxide into cyclic carbonates
An environmentally benign catalytic system consisting of 1, 8-diazabicyclo [5.4. 0]-undec-7-
ene (DBU) and cellulose was developed for CO2 chemical fixation with epoxides under …
ene (DBU) and cellulose was developed for CO2 chemical fixation with epoxides under …
En route to CO 2-containing renewable materials: catalytic synthesis of polycarbonates and non-isocyanate polyhydroxyurethanes derived from cyclic carbonates
Combining CO2-chemistry with biomass conversion allows renewable polymeric materials
including polycarbonates and polyhydroxyurethanes (PHUs) to be generated. The demand …
including polycarbonates and polyhydroxyurethanes (PHUs) to be generated. The demand …
Heterodinuclear Mg (II) M (II)(M= Cr, Mn, Fe, Co, Ni, Cu and Zn) complexes for the ring opening copolymerization of carbon dioxide/epoxide and anhydride/epoxide
The catalysed ring opening copolymerizations (ROCOP) of carbon dioxide/epoxide or
anhydride/epoxide are controlled polymerizations that access useful polycarbonates and …
anhydride/epoxide are controlled polymerizations that access useful polycarbonates and …
Correlating metal redox potentials to Co (III) K (I) catalyst performances in carbon dioxide and propene oxide ring opening copolymerization
Carbon dioxide copolymerization is a front‐runner CO2 utilization strategy but its viability
depends on improving the catalysis. So far, catalyst structure‐performance correlations have …
depends on improving the catalysis. So far, catalyst structure‐performance correlations have …
The Role of Water Revisited and Enhanced: A Sustainable Catalytic System for the Conversion of CO2 into Cyclic Carbonates under Mild Conditions
The role of water as highly effective hydrogen‐bond donor (HBD) for promoting the coupling
reaction of CO2 with a variety of epoxides was demonstrated under very mild conditions (25 …
reaction of CO2 with a variety of epoxides was demonstrated under very mild conditions (25 …
Highly active chromium complexes supported by constrained schiff-base ligands for cycloaddition of carbon dioxide to epoxides
J Kiriratnikom, N Laiwattanapaisarn… - Inorganic …, 2021 - ACS Publications
Novel constrained Schiff-base ligands (inden) were developed based on the well-known
salen ligands. Chromium complexes supported by the constrained inden ligands were …
salen ligands. Chromium complexes supported by the constrained inden ligands were …