Copolymerization of carbon dioxide and epoxides by metal coordination complexes

CM Kozak, K Ambrose, TS Anderson - Coordination Chemistry Reviews, 2018 - Elsevier
The catalytic copolymerization of CO 2 with epoxides to give polycarbonates was discovered
nearly 50 years ago. The last 10 years have been particularly exciting for the development …

Update and challenges in carbon dioxide‐based polycarbonate synthesis

J Huang, JC Worch, AP Dove, O Coulembier - ChemSusChem, 2020 - Wiley Online Library
The utilization of carbon dioxide as a comonomer to produce polycarbonates has attracted a
great deal of attention from both industrial and academic communities because it promises …

Intricacies of Cation–Anion Combinations in Imidazolium Salt-Catalyzed Cycloaddition of CO2 Into Epoxides

FD Bobbink, D Vasilyev, M Hulla, S Chamam… - ACS …, 2018 - ACS Publications
The cycloaddition of CO2 into epoxides catalyzed by imidazolium and related salts
continues to attract attention due to the industrial importance of the cyclic carbonate …

Green polycarbonates prepared by the copolymerization of CO2 with epoxides

M Taherimehr, PP Pescarmona - Journal of Applied Polymer …, 2014 - Wiley Online Library
Polycarbonates can be prepared by the copolymerization of epoxides with carbon dioxide
as an inexpensive, abundant, nontoxic, and renewable feedstock. This review covers the …

Superbase/cellulose: an environmentally benign catalyst for chemical fixation of carbon dioxide into cyclic carbonates

J Sun, W Cheng, Z Yang, J Wang, T Xu, J **n… - Green …, 2014 - pubs.rsc.org
An environmentally benign catalytic system consisting of 1, 8-diazabicyclo [5.4. 0]-undec-7-
ene (DBU) and cellulose was developed for CO2 chemical fixation with epoxides under …

Heterodinuclear Mg (II) M (II)(M= Cr, Mn, Fe, Co, Ni, Cu and Zn) complexes for the ring opening copolymerization of carbon dioxide/epoxide and anhydride/epoxide

NV Reis, AC Deacy, G Rosetto, CB Durr… - … A European Journal, 2022 - Wiley Online Library
The catalysed ring opening copolymerizations (ROCOP) of carbon dioxide/epoxide or
anhydride/epoxide are controlled polymerizations that access useful polycarbonates and …

Correlating metal redox potentials to Co (III) K (I) catalyst performances in carbon dioxide and propene oxide ring opening copolymerization

W Lindeboom, AC Deacy… - Angewandte Chemie …, 2023 - Wiley Online Library
Carbon dioxide copolymerization is a front‐runner CO2 utilization strategy but its viability
depends on improving the catalysis. So far, catalyst structure‐performance correlations have …

The Role of Water Revisited and Enhanced: A Sustainable Catalytic System for the Conversion of CO2 into Cyclic Carbonates under Mild Conditions

YA Alassmy, PP Pescarmona - ChemSusChem, 2019 - Wiley Online Library
The role of water as highly effective hydrogen‐bond donor (HBD) for promoting the coupling
reaction of CO2 with a variety of epoxides was demonstrated under very mild conditions (25 …

Highly active chromium complexes supported by constrained schiff-base ligands for cycloaddition of carbon dioxide to epoxides

J Kiriratnikom, N Laiwattanapaisarn… - Inorganic …, 2021 - ACS Publications
Novel constrained Schiff-base ligands (inden) were developed based on the well-known
salen ligands. Chromium complexes supported by the constrained inden ligands were …