Atomically precise colloidal metal nanoclusters and nanoparticles: fundamentals and opportunities

R **, C Zeng, M Zhou, Y Chen - Chemical reviews, 2016 - ACS Publications
Colloidal nanoparticles are being intensely pursued in current nanoscience research.
Nanochemists are often frustrated by the well-known fact that no two nanoparticles are the …

Atomically precise clusters of noble metals: emerging link between atoms and nanoparticles

I Chakraborty, T Pradeep - Chemical reviews, 2017 - ACS Publications
Atomically precise pieces of matter of nanometer dimensions composed of noble metals are
new categories of materials with many unusual properties. Over 100 molecules of this kind …

Atomically precise alloy nanoclusters: syntheses, structures, and properties

X Kang, Y Li, M Zhu, R ** - Chemical Society Reviews, 2020 - pubs.rsc.org
Metal nanoclusters fill the gap between discrete atoms and plasmonic nanoparticles,
providing unique opportunities for investigating the quantum effects and precise structure …

Recent developments in the investigation of driving forces for transforming coinage metal nanoclusters

X Zou, X Kang, M Zhu - Chemical Society Reviews, 2023 - pubs.rsc.org
Metal nanoclusters serve as an emerging class of modular nanomaterials. The
transformation of metal nanoclusters has been fully reflected in their studies from every …

Atomically precise metal nanoclusters: stable sizes and optical properties

R ** - Nanoscale, 2015 - pubs.rsc.org
Controlling nanoparticles with atomic precision has long been a major dream of
nanochemists. Breakthroughs have been made in the case of gold nanoparticles, at least for …

Atom‐Precise Heteroatom Core‐Tailoring of Nanoclusters for Enhanced Solar Hydrogen Generation

MS Bootharaju, CW Lee, G Deng, H Kim… - Advanced …, 2023 - Wiley Online Library
While core–shell nanomaterials are highly desirable for realizing enhanced optical and
catalytic properties, their synthesis with atomic‐level control is challenging. Here, the …

Roles of thiolate ligands in the synthesis, properties and catalytic application of gold nanoclusters

RR Nasaruddin, T Chen, N Yan, J **e - Coordination Chemistry Reviews, 2018 - Elsevier
Abstract Ultrasmall (< 2 nm) ligand-protected metal nanoclusters (NCs) have been an
emerging class of functional materials with rich coordination chemistry, finding increasing …

Self‐Assembly of Precision Noble Metal Nanoclusters: Hierarchical Structural Complexity, Colloidal Superstructures, and Applications

JV Rival, P Mymoona, KM Lakshmi, Nonappa… - Small, 2021 - Wiley Online Library
Ligand protected noble metal nanoparticles are excellent building blocks for colloidal self‐
assembly. Metal nanoparticle self‐assembly offers routes for a wide range of multifunctional …

Recent advances in the synthesis and catalytic applications of ligand-protected, atomically precise metal nanoclusters

J Fang, B Zhang, Q Yao, Y Yang, J **e… - Coordination Chemistry …, 2016 - Elsevier
Due to their excellent catalytic properties under mild reaction conditions, well-defined,
nanosized noble metal catalysts have potential applications in the manufacture of fine …

Molecule-like synthesis of ligand-protected metal nanoclusters

Q Yao, M Zhu, Z Yang, X Song, X Yuan… - Nature Reviews …, 2024 - nature.com
Ligand-protected metal nanoclusters (NCs) are ultrasmall particles (< 3 nm) that represent
the molecular state of metal materials. Owing to their molecule-like structure—particularly …