Photocontrolled RAFT polymerization: past, present, and future

Y Lee, C Boyer, MS Kwon - Chemical Society Reviews, 2023 - pubs.rsc.org
In this review, we provide a brief history, progress, and applications, and discuss the
remaining challenges of photocontrolled reversible addition–fragmentation chain transfer …

Recent developments and future challenges in controlled radical polymerization: a 2020 update

K Parkatzidis, HS Wang, NP Truong, A Anastasaki - Chem, 2020 - cell.com
This perspective summarizes the latest exciting developments in controlled radical
polymerization during the last decade (2010–2020). Our focus is to critically highlight …

Ultrasonics in polymer science: applications and challenges

ARSS Kumar, A Padmakumar, U Kalita… - Progress in Materials …, 2023 - Elsevier
Ultrasonic waves in a liquid media generate both chemical and mechanistic effects that are
actively used to perform chemical reactions, polymer synthesis, nanoparticle synthesis …

Progress and perspectives beyond traditional RAFT polymerization

MD Nothling, Q Fu, A Reyhani… - Advanced …, 2020 - Wiley Online Library
The development of advanced materials based on well‐defined polymeric architectures is
proving to be a highly prosperous research direction across both industry and academia …

Photo‐iniferter RAFT polymerization

M Hartlieb - Macromolecular Rapid Communications, 2022 - Wiley Online Library
Light‐mediated polymerization techniques offer distinct advantages over polymerization
reactions fueled by thermal energy, such as high spatial and temporal control as well as the …

Inverse Miniemulsion Enables the Continuous-Flow Synthesis of Controlled Ultra-High Molecular Weight Polymers

CLG Davidson IV, ME Lott, L Trachsel… - ACS Macro …, 2023 - ACS Publications
We report the controlled synthesis of ultra-high molecular weight (UHMW) polymers (M n≥
106 g/mol) via continuous flow in a tubular reactor. At high monomer conversion, UHMW …

Oxygen-enhanced atom transfer radical polymerization through the formation of a copper superoxido complex

K Parkatzidis, NP Truong, R Whitfield… - Journal of the …, 2023 - ACS Publications
In controlled radical polymerization, oxygen is typically regarded as an undesirable
component resulting in terminated polymer chains, deactivated catalysts, and subsequent …

An Atom‐Economic Enzymatic Cascade Catalysis for High‐Throughput RAFT Synthesis of Ultrahigh Molecular Weight Polymers

R Li, S Zhang, Q Li, GG Qiao… - Angewandte Chemie …, 2022 - Wiley Online Library
High‐throughput synthesis of well‐defined, ultrahigh molecular weight (UHMW) polymers by
green approaches is highly desirable but remains unexplored. We report the creation of an …

Divergent synthesis of graft and branched copolymers through spatially controlled photopolymerization in flow reactors

N Corrigan, FJ Trujillo, J Xu, G Moad, CJ Hawker… - …, 2021 - ACS Publications
In this work, we demonstrate the controlled synthesis of graft and branched copolymers
using one-pot (batch) or one-pass (flow) processes without intermediate purification. The …

Universal visible-light photoiniferter polymerization

S Lian, SP Armes, Z An - CCS Chemistry, 2024 - chinesechemsoc.org
Currently, there is no versatile method for the synthesis of high molecular weight (MW)
polymers by controlled radical polymerization from a broad range of monomers using a …