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Cation− π interaction: Its role and relevance in chemistry, biology, and material science
Noncovalent interactions are essential for the existence of solid and liquid phases. 1, 2
Traditionally touted as weak forces, quantification of these interactions, which govern the …
Traditionally touted as weak forces, quantification of these interactions, which govern the …
Binding mechanisms in supramolecular complexes
HJ Schneider - Angewandte Chemie International Edition, 2009 - Wiley Online Library
Forces to reckon with: Supramolecular complexes, such as the one shown, are normally
based on a combination of different interactions such as ion pairing, hydrogen bonds, and …
based on a combination of different interactions such as ion pairing, hydrogen bonds, and …
Cation− π interactions in organic synthesis
S Yamada - Chemical reviews, 2018 - ACS Publications
The cation− π interaction is an attractive noncovalent interaction between a cation and a π
system. Due to the stronger interaction energy than those of the other π interactions, such as …
system. Due to the stronger interaction energy than those of the other π interactions, such as …
Molecular balances for quantifying non-covalent interactions
IK Mati, SL Cockroft - Chemical Society Reviews, 2010 - pubs.rsc.org
Molecular interactions underlie the whole of chemistry and biology. This tutorial review
illustrates the use of rotameric folding molecules, topoisomers, atropoisomers, and …
illustrates the use of rotameric folding molecules, topoisomers, atropoisomers, and …
Nanomechanics of π-cation-π interaction with implications for bio-inspired wet adhesion
Cation-π interactions play a vital role in modulating various biological processes, eg,
potassium-selective channel, protein folding and adhesion of marine organism. Previous …
potassium-selective channel, protein folding and adhesion of marine organism. Previous …
External-stimuli responsive photophysics and liquid crystal properties of self-assembled “phosphole-lipids”
A series of new amphiphilic phosphonium materials that combine the electronic features of
phospholes with self-assembly features of lipids were synthesized. Variable concentration …
phospholes with self-assembly features of lipids were synthesized. Variable concentration …
Explicit solvent effect on cation− π interactions: a first principle investigation
JS Rao, H Zipse, GN Sastry - The Journal of Physical Chemistry B, 2009 - ACS Publications
Sequential attachment of water molecules to cation− π (Li+− benzene, K+− benzene, and
Mg2+− benzene) systems reveals that the cation− π interaction strength varies in opposite …
Mg2+− benzene) systems reveals that the cation− π interaction strength varies in opposite …
Partitioning solvophobic and dispersion forces in alkyl and perfluoroalkyl cohesion
Fluorocarbons often have distinct miscibility properties compared to their nonfluorinated
analogues. These differences may be attributed to van der Waals dispersion forces or …
analogues. These differences may be attributed to van der Waals dispersion forces or …
Versatile self-adapting boronic acids for H-bond recognition: from discrete to polymeric supramolecules
I Georgiou, S Kervyn, A Rossignon… - Journal of the …, 2017 - ACS Publications
Because of the peculiar dynamic covalent reactivity of boronic acids to form tetraboronate
derivatives, interest in using their aryl derivatives in materials science and supramolecular …
derivatives, interest in using their aryl derivatives in materials science and supramolecular …
Upregulation of BMSCs Osteogenesis by Positively-Charged Tertiary Amines on Polymeric Implants via Charge/iNOS Signaling Pathway
Positively-charged surfaces on implants have a similar potential to upregulate osteogenesis
of bone marrow-derived mesenchymal stem cells (BMSCs) as electromagnetic therapy …
of bone marrow-derived mesenchymal stem cells (BMSCs) as electromagnetic therapy …