Cation− π interaction: Its role and relevance in chemistry, biology, and material science

AS Mahadevi, GN Sastry - Chemical reviews, 2013 - ACS Publications
Noncovalent interactions are essential for the existence of solid and liquid phases. 1, 2
Traditionally touted as weak forces, quantification of these interactions, which govern the …

Binding mechanisms in supramolecular complexes

HJ Schneider - Angewandte Chemie International Edition, 2009 - Wiley Online Library
Forces to reckon with: Supramolecular complexes, such as the one shown, are normally
based on a combination of different interactions such as ion pairing, hydrogen bonds, and …

Cation− π interactions in organic synthesis

S Yamada - Chemical reviews, 2018 - ACS Publications
The cation− π interaction is an attractive noncovalent interaction between a cation and a π
system. Due to the stronger interaction energy than those of the other π interactions, such as …

Molecular balances for quantifying non-covalent interactions

IK Mati, SL Cockroft - Chemical Society Reviews, 2010 - pubs.rsc.org
Molecular interactions underlie the whole of chemistry and biology. This tutorial review
illustrates the use of rotameric folding molecules, topoisomers, atropoisomers, and …

Nanomechanics of π-cation-π interaction with implications for bio-inspired wet adhesion

L **ang, J Zhang, W Wang, L Gong, L Zhang, B Yan… - Acta Biomaterialia, 2020 - Elsevier
Cation-π interactions play a vital role in modulating various biological processes, eg,
potassium-selective channel, protein folding and adhesion of marine organism. Previous …

External-stimuli responsive photophysics and liquid crystal properties of self-assembled “phosphole-lipids”

Y Ren, WH Kan, MA Henderson… - Journal of the …, 2011 - ACS Publications
A series of new amphiphilic phosphonium materials that combine the electronic features of
phospholes with self-assembly features of lipids were synthesized. Variable concentration …

Explicit solvent effect on cation− π interactions: a first principle investigation

JS Rao, H Zipse, GN Sastry - The Journal of Physical Chemistry B, 2009 - ACS Publications
Sequential attachment of water molecules to cation− π (Li+− benzene, K+− benzene, and
Mg2+− benzene) systems reveals that the cation− π interaction strength varies in opposite …

Partitioning solvophobic and dispersion forces in alkyl and perfluoroalkyl cohesion

C Adam, L Yang, SL Cockroft - … Chemie International Edition, 2015 - Wiley Online Library
Fluorocarbons often have distinct miscibility properties compared to their nonfluorinated
analogues. These differences may be attributed to van der Waals dispersion forces or …

Versatile self-adapting boronic acids for H-bond recognition: from discrete to polymeric supramolecules

I Georgiou, S Kervyn, A Rossignon… - Journal of the …, 2017 - ACS Publications
Because of the peculiar dynamic covalent reactivity of boronic acids to form tetraboronate
derivatives, interest in using their aryl derivatives in materials science and supramolecular …

Upregulation of BMSCs Osteogenesis by Positively-Charged Tertiary Amines on Polymeric Implants via Charge/iNOS Signaling Pathway

W Zhang, N Liu, H Shi, J Liu, L Shi, B Zhang, H Wang… - Scientific reports, 2015 - nature.com
Positively-charged surfaces on implants have a similar potential to upregulate osteogenesis
of bone marrow-derived mesenchymal stem cells (BMSCs) as electromagnetic therapy …