Quasiparticle Self-Consistent GW-Bethe–Salpeter Equation Calculations for Large Chromophoric Systems

A Förster, L Visscher - Journal of chemical theory and …, 2022 - ACS Publications
The GW-Bethe–Salpeter equation (BSE) method is promising for calculating the low-lying
excitonic states of molecular systems. However, so far it has only been applied to rather …

Accelerating Analytic-Continuation GW Calculations with a Laplace Transform and Natural Auxiliary Functions

J Tölle, N Niemeyer… - Journal of Chemical Theory …, 2024 - ACS Publications
We present a simple and accurate GW implementation based on a combination of a Laplace
transform (LT) and other acceleration techniques used in post-self-consistent field quantum …

Particle–Particle Random Phase Approximation for Predicting Correlated Excited States of Point Defects

J Li, Y **, J Yu, W Yang, T Zhu - Journal of Chemical Theory and …, 2024 - ACS Publications
The particle–particle random phase approximation (ppRPA) within the hole–hole channel
was recently proposed as an efficient tool for computing excitation energies of point defects …

Excited-state properties for extended systems: efficient hybrid density functional methods

AS Hehn, B Sertcan, F Belleflamme… - Journal of chemical …, 2022 - ACS Publications
Time-dependent density functional theory has become state-of-the-art for describing
photophysical and photochemical processes in extended materials because of its affordable …

Hot carrier extraction from 2D semiconductor photoelectrodes

R Austin, YR Farah, T Sayer… - Proceedings of the …, 2023 - National Acad Sciences
Hot carrier-based energy conversion systems could double the efficiency of conventional
solar energy technology or drive photochemical reactions that would not be possible using …

Minimal auxiliary basis set approach for the electronic excitation spectra of organic molecules

Z Zhou, F Della Sala, SM Parker - The Journal of Physical …, 2023 - ACS Publications
We report a minimal auxiliary basis model for time-dependent density functional theory
(TDDFT) with hybrid density functionals that can accurately reproduce excitation energies …

Super-resolution techniques to simulate electronic spectra of large molecular systems

M Kick, E Alexander, A Beiersdorfer… - Nature …, 2024 - nature.com
An accurate treatment of electronic spectra in large systems with a technique such as time-
dependent density functional theory is computationally challenging. Due to the Nyquist …

Deterministic and Faster GW Calculations with a Reduced Number of Valence States: O(N2 ln N) Scaling in the Plane-Waves Formalism

S Cigagna, G Menegatti, P Umari - Journal of Chemical Theory …, 2024 - ACS Publications
We introduce a method for reducing the number of valence states entering the calculation of
screened the Coulomb interaction W in GW calculations. In this way, denoting with N the …

The eXact integral simplified time-dependent density functional theory (XsTD-DFT)

M de Wergifosse, S Grimme - The Journal of Chemical Physics, 2024 - pubs.aip.org
In the framework of simplified quantum chemistry methods, we introduce the eXact integral
simplified time-dependent density functional theory (XsTD-DFT). This method is based on …

Investigation of the Structure and Optical Properties of Polymethine-Based NIR-II Fluorophores Using Many-Body Perturbation Theory: GW-BSE Approaches

H Guo, NNT Pham, JS Park, SG Lee - The Journal of Physical …, 2024 - ACS Publications
Fluorescence imaging is a widely used technique for detecting pathophysiological
microenvironments and guiding fluorescence-guided therapy owing to its noninvasiveness …