Frustrated Lewis pair chemistry: development and perspectives

DW Stephan, G Erker - Angewandte Chemie International …, 2015 - Wiley Online Library
Abstract Frustrated Lewis pairs (FLPs) are combinations of Lewis acids and Lewis bases in
solution that are deterred from strong adduct formation by steric and/or electronic factors …

NHCs in main group chemistry

V Nesterov, D Reiter, P Bag, P Frisch, R Holzner… - Chemical …, 2018 - ACS Publications
Since the discovery of the first stable N-heterocyclic carbene (NHC) in the beginning of the
1990s, these divalent carbon species have become a common and available class of …

Frustrated lewis pairs

DW Stephan - Journal of the American Chemical Society, 2015 - ACS Publications
The articulation of the notion of “frustrated Lewis pairs”(FLPs), which emerged from the
discovery that H2 can be reversibly activated by combinations of sterically encumbered …

N-heterocyclic carbene adducts of main group elements and their use as ligands in transition metal chemistry

A Doddi, M Peters, M Tamm - Chemical reviews, 2019 - ACS Publications
N-Heterocyclic carbenes (NHC) are nowadays ubiquitous and indispensable in many
research fields, and it is not possible to imagine modern transition metal and main group …

Progress and challenges in nitrous oxide decomposition and valorization

X Wu, J Du, Y Gao, H Wang, C Zhang… - Chemical Society …, 2024 - pubs.rsc.org
Nitrous oxide (N2O) decomposition is increasingly acknowledged as a viable strategy for
mitigating greenhouse gas emissions and addressing ozone depletion, aligning significantly …

Frustrated Lewis pair chemistry of carbon, nitrogen and sulfur oxides

DW Stephan, G Erker - Chemical Science, 2014 - pubs.rsc.org
Frustrated Lewis pairs have been used to activate a variety of small molecules. In this review
we focus on the recent chemistry of FLPs with CO2, CO, N2O, NO and SO2. While FLP …

Catalytic Activation of N2O at a Low-Valent Bismuth Redox Platform

Y Pang, M Leutzsch, N Nöthling… - Journal of the American …, 2020 - ACS Publications
Herein we present the catalytic activation of N2O at a BiI⇄ BiIII redox platform. The activation
of such a kinetically inert molecule was achieved by the use of bismuthinidene catalysts …

Persistent Radicals Derived from N-Heterocyclic Carbenes for Material Applications

H Song, E Pietrasiak, E Lee - Accounts of Chemical Research, 2022 - ACS Publications
Conspectus Persistent radicals are potential building blocks of novel materials in many
fields. Recently, highly stable persistent radicals are considered to be within reach, thanks to …

Nitrous oxide as diazo transfer reagent

A Genoux, K Severin - Chemical Science, 2024 - pubs.rsc.org
Nitrous oxide, commonly known as “laughing gas”, is formed as a by-product in several
industrial processes. It is also readily available by thermal decomposition of ammonium …

Polymeric nitric oxide delivery nanoplatforms for treating cancer, cardiovascular diseases, and infection

G **, Z Gao, Y Liu, J Zhao, H Ou… - Advanced Healthcare …, 2021 - Wiley Online Library
The shortened Abstract is as follows: Therapeutic gas nitric oxide (NO) has demonstrated
the unique advances in biomedical applications due to its prominent role in regulating …