Frustrated Lewis pair chemistry: development and perspectives
DW Stephan, G Erker - Angewandte Chemie International …, 2015 - Wiley Online Library
Abstract Frustrated Lewis pairs (FLPs) are combinations of Lewis acids and Lewis bases in
solution that are deterred from strong adduct formation by steric and/or electronic factors …
solution that are deterred from strong adduct formation by steric and/or electronic factors …
NHCs in main group chemistry
V Nesterov, D Reiter, P Bag, P Frisch, R Holzner… - Chemical …, 2018 - ACS Publications
Since the discovery of the first stable N-heterocyclic carbene (NHC) in the beginning of the
1990s, these divalent carbon species have become a common and available class of …
1990s, these divalent carbon species have become a common and available class of …
Frustrated lewis pairs
DW Stephan - Journal of the American Chemical Society, 2015 - ACS Publications
The articulation of the notion of “frustrated Lewis pairs”(FLPs), which emerged from the
discovery that H2 can be reversibly activated by combinations of sterically encumbered …
discovery that H2 can be reversibly activated by combinations of sterically encumbered …
N-heterocyclic carbene adducts of main group elements and their use as ligands in transition metal chemistry
N-Heterocyclic carbenes (NHC) are nowadays ubiquitous and indispensable in many
research fields, and it is not possible to imagine modern transition metal and main group …
research fields, and it is not possible to imagine modern transition metal and main group …
Progress and challenges in nitrous oxide decomposition and valorization
X Wu, J Du, Y Gao, H Wang, C Zhang… - Chemical Society …, 2024 - pubs.rsc.org
Nitrous oxide (N2O) decomposition is increasingly acknowledged as a viable strategy for
mitigating greenhouse gas emissions and addressing ozone depletion, aligning significantly …
mitigating greenhouse gas emissions and addressing ozone depletion, aligning significantly …
Frustrated Lewis pair chemistry of carbon, nitrogen and sulfur oxides
DW Stephan, G Erker - Chemical Science, 2014 - pubs.rsc.org
Frustrated Lewis pairs have been used to activate a variety of small molecules. In this review
we focus on the recent chemistry of FLPs with CO2, CO, N2O, NO and SO2. While FLP …
we focus on the recent chemistry of FLPs with CO2, CO, N2O, NO and SO2. While FLP …
Catalytic Activation of N2O at a Low-Valent Bismuth Redox Platform
Y Pang, M Leutzsch, N Nöthling… - Journal of the American …, 2020 - ACS Publications
Herein we present the catalytic activation of N2O at a BiI⇄ BiIII redox platform. The activation
of such a kinetically inert molecule was achieved by the use of bismuthinidene catalysts …
of such a kinetically inert molecule was achieved by the use of bismuthinidene catalysts …
Persistent Radicals Derived from N-Heterocyclic Carbenes for Material Applications
Conspectus Persistent radicals are potential building blocks of novel materials in many
fields. Recently, highly stable persistent radicals are considered to be within reach, thanks to …
fields. Recently, highly stable persistent radicals are considered to be within reach, thanks to …
Nitrous oxide as diazo transfer reagent
Nitrous oxide, commonly known as “laughing gas”, is formed as a by-product in several
industrial processes. It is also readily available by thermal decomposition of ammonium …
industrial processes. It is also readily available by thermal decomposition of ammonium …
Polymeric nitric oxide delivery nanoplatforms for treating cancer, cardiovascular diseases, and infection
The shortened Abstract is as follows: Therapeutic gas nitric oxide (NO) has demonstrated
the unique advances in biomedical applications due to its prominent role in regulating …
the unique advances in biomedical applications due to its prominent role in regulating …