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Recent advances in palladium-catalyzed isocyanide insertions
Isocyanides have long been known as versatile chemical reagents in organic synthesis.
Their ambivalent nature also allows them to function as a CO-substitute in palladium …
Their ambivalent nature also allows them to function as a CO-substitute in palladium …
Macromolecular superstructures: a future beyond single chain nanoparticles
Over the last 100 years polymer chemistry has flourished in all areas and enabled control
over synthetic polymer architectures–including chain lengths, dispersity and monomer …
over synthetic polymer architectures–including chain lengths, dispersity and monomer …
Molecular Insights into [2.2] Paracyclophane‐Based Functional Materials: Chemical Aspects Behind Functions
Z Hassan - Advanced Functional Materials, 2024 - Wiley Online Library
Many of the functions and features of practically useful materials are the province of
molecular‐level chemistry and their modulation at different length‐scale. This report …
molecular‐level chemistry and their modulation at different length‐scale. This report …
Selective Synthesis of Single‐Handed Helical Polymers from Achiral Monomer and a Mechanism Study on Helix‐Sense‐Selective Polymerization
L Zhou, XH Xu, ZQ Jiang, L Xu, BF Chu… - Angewandte …, 2021 - Wiley Online Library
Inspired by the exquisite helices in Nature, fabrication of helical materials with controlled
handedness has attracted considerable attention. Herein, we report on precis synthesis of …
handedness has attracted considerable attention. Herein, we report on precis synthesis of …
Secondary structure in nonpeptidic supramolecular block copolymers
Conspectus Proteins contain a level of complexity—secondary and tertiary structures—that
polymer chemists aim to imitate. The bottom-up synthesis of protein-mimicking polymers …
polymer chemists aim to imitate. The bottom-up synthesis of protein-mimicking polymers …
Facile synthesis of cyanide and isocyanides from CO
The reaction of K [N (SiMe3) 2] with 13CO proceeds in C6D6 or THF affording K13CN and O
(SiMe3) 2 under mild conditions as confirmed by crystallographic characterization of K (18 …
(SiMe3) 2 under mild conditions as confirmed by crystallographic characterization of K (18 …
Synthesis and Polymerization of an ortho-para-Substituted Tetraalkoxy [2.2]Paracyclophane-1,9-diene
This contribution describes the synthesis of an unsymmetrical substituted tetraalkoxy [2.2]
paracyclophane-1, 9-diene comprised of an ortho-substituted and a para-substituted …
paracyclophane-1, 9-diene comprised of an ortho-substituted and a para-substituted …
Wavelength‐Selective Folding of Single Polymer Chains with Different Colors of Visible Light
Photochemistry allows chemists to exert control over chemical reactions with spatiotemporal
precision. Furthermore, light holds the potential to not only gate when and where but also …
precision. Furthermore, light holds the potential to not only gate when and where but also …
Folded Well‐Defined 3D Architecture from Synthetic Helical and Sheet‐Like Polymers
The fabrication of truly hierarchically folded single‐chain polymeric nanoparticles with
primary, secondary, and defined 3D architecture is still an unfulfilled goal. In this …
primary, secondary, and defined 3D architecture is still an unfulfilled goal. In this …
Orthogonal Supramolecular Assemblies Using Side-Chain Functionalized Helical Poly (isocyanide) s
Mimicking the structure of proteins using synthetic polymers requires building blocks with
structural similarity and the use of various noncovalent and dynamic covalent interactions …
structural similarity and the use of various noncovalent and dynamic covalent interactions …