Metal–organic frameworks and covalent organic frameworks as disruptive membrane materials for energy-efficient gas separation

AA Knebel, J Caro - Nature Nanotechnology, 2022 - nature.com
In this Review we survey the molecular sieving behaviour of metal–organic framework
(MOF) and covalent organic framework (COF) membranes, which is different from that of …

Confinement of luminescent guests in metal–organic frameworks: understanding pathways from synthesis and multimodal characterization to potential applications of …

M Gutiérrez, Y Zhang, JC Tan - Chemical Reviews, 2022 - ACS Publications
This review gives an authoritative, critical, and accessible overview of an emergent class of
fluorescent materials termed “LG@ MOF”, engineered from the nanoscale confinement of …

Power of infrared and raman spectroscopies to characterize metal-organic frameworks and investigate their interaction with guest molecules

KI Hadjiivanov, DA Panayotov, MY Mihaylov… - Chemical …, 2020 - ACS Publications
The variety of functionalities and porous structures inherent to metal-organic frameworks
(MOFs) together with the facile tunability of their properties makes these materials suitable …

Destruction of metal–organic frameworks: positive and negative aspects of stability and lability

L Feng, KY Wang, GS Day, MR Ryder… - Chemical …, 2020 - ACS Publications
Metal–organic frameworks (MOFs), constructed from organic linkers and inorganic building
blocks, are well-known for their high crystallinity, high surface areas, and high component …

Molecular recognition with resolution below 0.2 angstroms through thermoregulatory oscillations in covalent organic frameworks

Y Hu, B Sengupta, H Long, LJ Wayment, R Ciora, Y **… - Science, 2024 - science.org
Crystalline materials with uniform molecular-sized pores are desirable for a broad range of
applications, such as sensors, catalysis, and separations. However, it is challenging to tune …

Exploring the Structural, Dynamic, and Functional Properties of Metal‐Organic Frameworks through Molecular Modeling

F Formalik, K Shi, F Joodaki, X Wang… - Advanced Functional …, 2024 - Wiley Online Library
This review spotlights the role of atomic‐level modeling in research on metal‐organic
frameworks (MOFs), especially the key methodologies of density functional theory (DFT) …

Defibrillation of soft porous metal-organic frameworks with electric fields

A Knebel, B Geppert, K Volgmann, DI Kolokolov… - Science, 2017 - science.org
Gas transport through metal-organic framework membranes (MOFs) was switched in situ by
applying an external electric field (E-field). The switching of gas permeation upon E-field …

Zeolite membranes–a review and comparison with MOFs

N Rangnekar, N Mittal, B Elyassi, J Caro… - Chemical Society …, 2015 - pubs.rsc.org
The latest developments in zeolite membranes are reviewed, with an emphasis on the
synthesis techniques, including seed assembly and secondary growth methods. This review …

Topologically guided tuning of Zr-MOF pore structures for highly selective separation of C6 alkane isomers

H Wang, X Dong, J Lin, SJ Teat, S Jensen… - Nature …, 2018 - nature.com
As an alternative technology to energy intensive distillations, adsorptive separation by
porous solids offers lower energy cost and higher efficiency. Herein we report a topology …

Current trends in metal–organic and covalent organic framework membrane materials

B Hosseini Monjezi, K Kutonova… - Angewandte Chemie …, 2021 - Wiley Online Library
Metal–organic frameworks (MOFs) and covalent organic frameworks (COFs) have been
thoroughly investigated with regards to applications in gas separation membranes in the …