Recent advances in asymmetric borylation by transition metal catalysis
J Hu, M Ferger, Z Shi, TB Marder - Chemical Society Reviews, 2021 - pubs.rsc.org
Chiral organoboronates have played a critical role in organic chemistry and in the
development of materials science and pharmaceuticals. Much effort has been devoted to …
development of materials science and pharmaceuticals. Much effort has been devoted to …
Recent strategies in the nucleophilic dearomatization of pyridines, quinolines, and isoquinolines
M Escolano, D Gaviña, G Alzuet-Piña… - Chemical …, 2024 - ACS Publications
Dearomatization reactions have become fundamental chemical transformations in organic
synthesis since they allow for the generation of three-dimensional complexity from two …
synthesis since they allow for the generation of three-dimensional complexity from two …
Copper-boryl mediated organic synthesis
Organoboron compounds are valuable synthetic intermediates that find application in a
diverse variety of processes including both C–X and C–C bond-forming transformations …
diverse variety of processes including both C–X and C–C bond-forming transformations …
Copper-catalyzed functionalization of 1, 3-dienes: hydrofunctionalization, borofunctionalization, and difunctionalization
The catalytic conversion of chemical feedstocks into products of medicinal and agricultural
value is a key theme across modern synthetic chemistry. As 1, 3-dienes are readily available …
value is a key theme across modern synthetic chemistry. As 1, 3-dienes are readily available …
Sha** molecular landscapes: recent advances, opportunities, and challenges in dearomatization
CJ Huck, D Sarlah - Chem, 2020 - cell.com
Dearomatization is a fundamental chemical transformation, and it underlies some of the
most efficient tactics for generating three-dimensional complexity from basic two …
most efficient tactics for generating three-dimensional complexity from basic two …
Asymmetric synthesis of secondary and tertiary boronic esters
BSL Collins, CM Wilson, EL Myers… - Angewandte Chemie …, 2017 - Wiley Online Library
Non‐racemic chiral boronic esters are recognised as immensely valuable building blocks in
modern organic synthesis. Their stereospecific transformation into a variety of functional …
modern organic synthesis. Their stereospecific transformation into a variety of functional …
Catalytic enantio-and regioselective addition of nucleophiles in the intermolecular hydrofunctionalization of 1, 3-dienes
NJ Adamson, SJ Malcolmson - ACS Catalysis, 2019 - ACS Publications
Catalytic enantioselective synthesis of small-molecule building blocks with allylic
stereogenic centers is an important objective in organic synthesis, but preparing this motif …
stereogenic centers is an important objective in organic synthesis, but preparing this motif …
Oxidative dearomatization of pyridines
Z Siddiqi, TW Bingham, T Shimakawa… - Journal of the …, 2024 - ACS Publications
Dearomatization of pyridines is a well-established synthetic approach to access piperidines.
Although remarkably powerful, existing dearomatization processes have been limited to the …
Although remarkably powerful, existing dearomatization processes have been limited to the …
Highly Selective and Catalytic Generation of Acyclic Quaternary Carbon Stereocenters via Functionalization of 1,3-Dienes with CO2
The catalytic asymmetric functionalization of readily available 1, 3-dienes is highly important,
but current examples are mostly limited to the construction of tertiary chiral centers. The …
but current examples are mostly limited to the construction of tertiary chiral centers. The …
Regio‐and Diastereoselective Synthesis of Polysubstituted Piperidines Enabled by Boronyl Radical‐Catalyzed (4+ 2) Cycloaddition
Z Ding, Z Wang, Y Wang, X Wang, Y Xue… - Angewandte …, 2024 - Wiley Online Library
Piperidines are widely present in small molecule drugs and natural products. Despite many
methods have been developed for their synthesis, new approaches to polysubstituted …
methods have been developed for their synthesis, new approaches to polysubstituted …