s-Block metal catalysts for the hydroboration of unsaturated bonds
The addition of a B–H bond to an unsaturated bond (polarized or unpolarized) is a powerful
and atom-economic tool for the synthesis of organoboranes. In recent years, s-block …
and atom-economic tool for the synthesis of organoboranes. In recent years, s-block …
Organic synthesis with the most abundant transition metal–iron: from rust to multitasking catalysts
In industries and academic laboratories, several late transition metal-catalyzed prerequisite
reactions are widely performed during single and multistep synthesis. However, besides the …
reactions are widely performed during single and multistep synthesis. However, besides the …
Recent advances in the catalytic hydroboration of carbonyl compounds
The chemoselective catalytic hydroboration of aldehydes and ketones has found
widespread applications in organic chemistry due to the synthetic utility of borate ester …
widespread applications in organic chemistry due to the synthetic utility of borate ester …
Low-valent group 14 element hydride chemistry: towards catalysis
The chemistry of group 14 element (II) hydride complexes has rapidly expanded since the
first stable example of such a compound was reported in 2000. Since that time it has …
first stable example of such a compound was reported in 2000. Since that time it has …
Magnesium hydridotriphenylborate [Mg (thf) 6][HBPh 3] 2: a versatile hydroboration catalyst
D Mukherjee, S Shirase, TP Spaniol… - Chemical …, 2016 - pubs.rsc.org
Magnesium hydridotriphenylborate [Mg(thf) 6 ][HBPh 3 ] 2 : a versatile hydroboration catalyst -
Chemical Communications (RSC Publishing) DOI:10.1039/C6CC06805G Royal Society of …
Chemical Communications (RSC Publishing) DOI:10.1039/C6CC06805G Royal Society of …
Cyclic (alkyl)(amino) carbene ligand-promoted nitro deoxygenative hydroboration with chromium catalysis: scope, mechanism, and applications
Transition metal catalysis that utilizes N-heterocyclic carbenes as noninnocent ligands in
promoting transformations has not been well studied. We report here a cyclic (alkyl)(amino) …
promoting transformations has not been well studied. We report here a cyclic (alkyl)(amino) …
Dialumenes–aryl vs. silyl stabilisation for small molecule activation and catalysis
Main group multiple bonds have proven their ability to act as transition metal mimics in the
last few decades. However, catalytic application of these species is still in its infancy. Herein …
last few decades. However, catalytic application of these species is still in its infancy. Herein …
Zinc and magnesium catalysts for the hydrosilylation of carbon dioxide
M Rauch, G Parkin - Journal of the American Chemical Society, 2017 - ACS Publications
The terminal zinc and magnesium hydride compounds,[κ3-TismPriBenz] ZnH and
[TismPriBenz] MgH, which feature the tris [(1-isopropylbenzimidazol-2-yl) dimethylsilyl] …
[TismPriBenz] MgH, which feature the tris [(1-isopropylbenzimidazol-2-yl) dimethylsilyl] …
[BOOK][B] Early main group metal catalysis: concepts and reactions
S Harder - 2019 - books.google.com
Early Main Group Metal Catalysis gives a comprehensive overview of catalytic reactions in
the presence of group 1 and group 2 metals. Chapters are ordered to reaction type, contain …
the presence of group 1 and group 2 metals. Chapters are ordered to reaction type, contain …
Catalytic hydroboration of aldehydes, ketones, alkynes and alkenes initiated by NaOH
Commercially available NaOH powder is shown to be an efficient transition-metal-free
initiator for the catalytic hydroboration of aldehydes, ketones, alkynes and alkenes with …
initiator for the catalytic hydroboration of aldehydes, ketones, alkynes and alkenes with …