The design and construction of high-nuclear polyoxometalate (POM) clusters remain a
severe challenge, but attract significant interest on account of their impressive structural …

Polyoxometalates (POMs) are composed of cations and polyanion clusters 1 with structural
diversity, in which the oxometal polyhedra of MOx (x= 5, 6) are the basic construction units …

The hierarchical aggregation of molecular nanostructures from multiple components is a
grand synthetic challenge, which requires highly selective linkage control. We demonstrate …

The sustainable production of clean energy constitutes one of the most important scientific
challenges of the 21st century. Currently, the major part of the global energy supply is …

Only rarely have polyoxometalates been found to form core–shell nanoclusters. Here, we
succeeded in isolating a series of rare giant and all‐inorganic core–shell cobalt …

Polyoxometalates are clusters of metal-oxide units, comprising a large diversity of nanoscale
structures, and have many common building blocks; in fact polyoxometalate clusters are …

This review is intended to provide an up-to-date and comprehensive description of recent
advances since the mid-2010s in the elaboration and the involvement of polyoxometalates …

During the past decade, research into transition-metal-substituted polyoxometalate self-
assembly has been greatly developed. This review summarizes the conventional solution …

A series of all-inorganic, abundant-metal-based, high-nuclearity cobalt–phosphate (Co–Pi)
molecular catalysts [{Co4 (OH) 3 (PO4)} 4 (SiW9O34) 4] 32–(1),[{Co4 (OH) 3 (PO4)} 4 …

Polyoxometalates (POMs) are a series of molecular metal oxide clusters, which span the two
domains of solutes and solid metal oxides. The unique characters of POMs in structure …