Cobalt-catalyzed reductive alkynylation to construct C (sp)-C (sp3) and C (sp)-C (sp2) bonds

L Wan, Y Tong, X Lu, Y Fu - Chinese Chemical Letters, 2024 - Elsevier
Transition-metal-catalyzed cross-electrophile coupling has emerged as a reliable method for
constructing carbon–carbon bonds. Herein, we report a general method, cobalt-catalyzed …

Phenoxythiazoline (FTz)‐Cobalt(II) Precatalysts Enable C(sp2)–C(sp3) Bond‐Formation for Key Intermediates in the Synthesis of Toll‐like Receptor 7/8 Antagonists …

LR Mills, F Di Mare, D Gygi, H Lee… - Angewandte …, 2023 - Wiley Online Library
Abstract Evaluation of the relative rates of the cobalt‐catalyzed C (sp2)–C (sp3) Suzuki–
Miyaura cross‐coupling between the neopentylglycol ester of 4‐fluorophenylboronic acid …

Cobalt-Catalyzed C–C Coupling Reactions with Csp3 Electrophiles

J Li - CC Cross Couplings with 3d Base Metal Catalysts, 2023 - Springer
Carbon–carbon bond construction is a long-standing challenge in synthetic organic
chemistry. In the recent years, transition-metal-catalyzed C–C bond forming reactions have …

Palladium-catalyzed C–H dimethylamination of 1-chloromethyl naphthalenes with N, N-dimethylformamide as the dimethyl amino source

S Zhang, Z Wang, Y Gao, M Yamaguchi… - Organic & Biomolecular …, 2023 - pubs.rsc.org
Palladium-catalyzed remote C–H dimethylamination of 1-chloromethylnaphthalenes using
N, N-dimethylformamide as the dimethylamino source is described for the first time. The …

Up-Scale Synthesis of p-(CH2═CH)C6H4CH2CH2CH2Cl and p-ClC6H4SiR3 by CuCN-Catalyzed Coupling Reactions of Grignard Reagents with …

JY Park, JH Ko, HJ Lee, JH Park, J Lee, S Sa… - ACS …, 2022 - ACS Publications
Grignard reagents featuring carbanion characteristics are mostly unreactive toward alkyl
halides and require a catalyst for the coupling reaction. With the need to prepare p-(CH2═ …

Metal‐Free Oxidative Cross‐Dehydrogenative Coupling of Alkenes with Thiophenols

C Li, M Liao, Z He, Y Chen, J Mai, R Dong… - …, 2023 - Wiley Online Library
A novel transition‐metal‐free regioselective allylic C− H thiolation of alkenes has been
achieved by cross‐dehydrogenative coupling strategy. The present protocol realizes …

Triplet State‐Promoted Kumada‐Corriu Coupling Catalyzed by Hydrotris (3, 5‐diisopropylpyrazolyl) boratocobalt (III) diiodide

Z Wang, Y Cornaton, JP Djukic - European Journal of Inorganic …, 2024 - Wiley Online Library
Abstract The Kumada‐Corriu hetero‐coupling between an halogeno‐arene and an
arylmagnesiumbromide can be catalyzed with yields> 80% by the new hydrotris (3, 5 …

Cobalt-doped iron-based coordination polymer catalyst with unique shell-shaped agglomerate for enhancing the reaction activity of Kumada-coupling

D Hu, JQ Zhang, J Song, B Ni, H Ren - Journal of Solid State Chemistry, 2022 - Elsevier
Metal organic coordination polymers (MOCPs) with versatile structural topologies and
flexible design of metal active sites have been considered as suitable heterogeneous …

Phenoxythiazoline (FTz)–Cobalt (II) Precatalysts Enable C (sp2)–C (sp3) Bond–Formation for the Key Intermediate in the Synthesis of Afimetoran and Related Toll-like …

LR Mills, F DiMare, D Gygi, H Lee, EM Simmons, J Kim… - 2023 - chemrxiv.org
Evaluation of the relative rates of the cobalt-catalyzed C (sp2)–C (sp3) Suzuki–Miyaura
cross-coupling between the neopentylglycol ester of 4-fluorophenylboronic acid and N-Boc …

Recyclable Cobalt-Doped Iron-Based Coordination Polymer Catalyst with Unique Shell-Shaped Agglomerate for Enhancing the Reaction Activity of Kumada-Coupling

JQ Zhang, J Song, B Ni, H Ren - papers.ssrn.com
Metal organic coordination polymers (MOCPs) with versatile structural topologies and
flexible design of metal active sites have been considered as suitable heterogeneous …