Metal–organic frameworks in heterogeneous catalysis: recent progress, new trends, and future perspectives

A Bavykina, N Kolobov, IS Khan, JA Bau… - Chemical …, 2020 - ACS Publications
More than 95%(in volume) of all of today's chemical products are manufactured through
catalytic processes, making research into more efficient catalytic materials a thrilling and …

Metal–organic framework-based catalysts with single metal sites

YS Wei, M Zhang, R Zou, Q Xu - Chemical Reviews, 2020 - ACS Publications
Metal–organic frameworks (MOFs) are a class of distinctive porous crystalline materials
constructed by metal ions/clusters and organic linkers. Owing to their structural diversity …

Introducing Frustrated Lewis Pairs to Metal–Organic Framework for Selective Hydrogenation of N-Heterocycles

ZM Xu, Z Hu, Y Huang, SJ Bao, Z Niu… - Journal of the …, 2023 - ACS Publications
Hydrogenated nitrogen heterocyclic compounds play a critical role in the pharmaceutical,
polymer, and agrochemical industries. Recent studies on partial hydrogenation of nitrogen …

Metal–organic frameworks as catalysts for organic synthesis: a critical perspective

V Pascanu, G González Miera, AK Inge… - Journal of the …, 2019 - ACS Publications
Recent advances in organic chemistry and materials chemistry have enabled the porosity of
new materials to be accurately controlled on the nanometer scale. In this context, metal …

Recent advances in catalytic transfer hydrogenation with formic acid over heterogeneous transition metal catalysts

R Nie, Y Tao, Y Nie, T Lu, J Wang, Y Zhang, X Lu… - ACS …, 2021 - ACS Publications
Transition-metal-catalyzed transfer hydrogenation with an in situ hydrogen donor has
received a great deal of attention from both academia and industry as an alternative to the …

Reticular chemistry in the rational synthesis of functional zirconium cluster-based MOFs

Z Chen, SL Hanna, LR Redfern, D Alezi… - Coordination Chemistry …, 2019 - Elsevier
In the past two decades, reticular chemistry has developed into a powerful tool for the design
and synthesis of porous, crystalline framework materials. The discovery of the first …

Key factors in pincer ligand design

E Peris, RH Crabtree - Chemical Society Reviews, 2018 - pubs.rsc.org
Pincers, tridentate ligands that prefer a meridional geometry, are a rising class because of
their distinctive combination of properties. They permit a good level of control on the nature …

Conceptual and practical aspects of metal–organic frameworks for solid–gas reactions

A Iliescu, JJ Oppenheim, C Sun, M Dincǎ - Chemical Reviews, 2023 - ACS Publications
The presence of site-isolated and well-defined metal sites has enabled the use of metal–
organic frameworks (MOFs) as catalysts that can be rationally modulated. Because MOFs …

Topologically guided tuning of Zr-MOF pore structures for highly selective separation of C6 alkane isomers

H Wang, X Dong, J Lin, SJ Teat, S Jensen… - Nature …, 2018 - nature.com
As an alternative technology to energy intensive distillations, adsorptive separation by
porous solids offers lower energy cost and higher efficiency. Herein we report a topology …

Catalytic zirconium/hafnium-based metal–organic frameworks

M Rimoldi, AJ Howarth, MR DeStefano, L Lin… - Acs …, 2017 - ACS Publications
Metal–organic frameworks (MOFs) are highly versatile materials that find applications in
several fields. Highly stable zirconium/hafnium-based MOFs were recently introduced and …