Metal–organic frameworks in heterogeneous catalysis: recent progress, new trends, and future perspectives
More than 95%(in volume) of all of today's chemical products are manufactured through
catalytic processes, making research into more efficient catalytic materials a thrilling and …
catalytic processes, making research into more efficient catalytic materials a thrilling and …
Metal–organic framework-based catalysts with single metal sites
Metal–organic frameworks (MOFs) are a class of distinctive porous crystalline materials
constructed by metal ions/clusters and organic linkers. Owing to their structural diversity …
constructed by metal ions/clusters and organic linkers. Owing to their structural diversity …
Introducing Frustrated Lewis Pairs to Metal–Organic Framework for Selective Hydrogenation of N-Heterocycles
ZM Xu, Z Hu, Y Huang, SJ Bao, Z Niu… - Journal of the …, 2023 - ACS Publications
Hydrogenated nitrogen heterocyclic compounds play a critical role in the pharmaceutical,
polymer, and agrochemical industries. Recent studies on partial hydrogenation of nitrogen …
polymer, and agrochemical industries. Recent studies on partial hydrogenation of nitrogen …
Metal–organic frameworks as catalysts for organic synthesis: a critical perspective
Recent advances in organic chemistry and materials chemistry have enabled the porosity of
new materials to be accurately controlled on the nanometer scale. In this context, metal …
new materials to be accurately controlled on the nanometer scale. In this context, metal …
Recent advances in catalytic transfer hydrogenation with formic acid over heterogeneous transition metal catalysts
R Nie, Y Tao, Y Nie, T Lu, J Wang, Y Zhang, X Lu… - ACS …, 2021 - ACS Publications
Transition-metal-catalyzed transfer hydrogenation with an in situ hydrogen donor has
received a great deal of attention from both academia and industry as an alternative to the …
received a great deal of attention from both academia and industry as an alternative to the …
Reticular chemistry in the rational synthesis of functional zirconium cluster-based MOFs
In the past two decades, reticular chemistry has developed into a powerful tool for the design
and synthesis of porous, crystalline framework materials. The discovery of the first …
and synthesis of porous, crystalline framework materials. The discovery of the first …
Key factors in pincer ligand design
Pincers, tridentate ligands that prefer a meridional geometry, are a rising class because of
their distinctive combination of properties. They permit a good level of control on the nature …
their distinctive combination of properties. They permit a good level of control on the nature …
Conceptual and practical aspects of metal–organic frameworks for solid–gas reactions
The presence of site-isolated and well-defined metal sites has enabled the use of metal–
organic frameworks (MOFs) as catalysts that can be rationally modulated. Because MOFs …
organic frameworks (MOFs) as catalysts that can be rationally modulated. Because MOFs …
Topologically guided tuning of Zr-MOF pore structures for highly selective separation of C6 alkane isomers
As an alternative technology to energy intensive distillations, adsorptive separation by
porous solids offers lower energy cost and higher efficiency. Herein we report a topology …
porous solids offers lower energy cost and higher efficiency. Herein we report a topology …
Catalytic zirconium/hafnium-based metal–organic frameworks
Metal–organic frameworks (MOFs) are highly versatile materials that find applications in
several fields. Highly stable zirconium/hafnium-based MOFs were recently introduced and …
several fields. Highly stable zirconium/hafnium-based MOFs were recently introduced and …