The oxygen‐evolving center (OEC) in photosystem II (PSII) is a unique biological catalyst
that splits water into electrons, protons, and O2 by using solar energy. Recent …

Pendent metals bound to heterocubanes are components of well-known active sites in
enzymes that mediate difficult chemical transformations. Investigations into the specific role …

Abstract The natural Mn4Ca cluster in photosystem II serves as a blueprint to develop
artificial water‐splitting catalysts for the generation of solar fuel in artificial photosynthesis …

We report the single crystal XRD and MicroED structure, magnetic susceptibility, and EPR
data of a series of CaMn3IVO4 and YMn3IVO4 complexes as structural and spectroscopic …

Biomimetic catalysts, ranging from small‐molecule metal complexes to supramolecular
assembles, possess many exciting properties that could address salient challenges in …

Despite extensive biochemical, spectroscopic, and computational studies, the mechanism of
biological water oxidation by the oxygen evolving complex (OEC) of Photosystem II remains …

In this Concept article we present the syntheses and application of homo and
heterodinuclear “Pacman” compounds. This architecture implies that two metal coordination …

The S3 state is currently the last observable intermediate prior to O–O bond formation at the
oxygen-evolving complex (OEC) of Photosystem II, and its electronic structure has been …

In polynuclear biological active sites, multiple electrons are needed for turnover, and the
distribution of these electrons among the metal sites is affected by the structure of the active …

The photosynthetic oxygen‐evolving center (OEC) is a unique Mn4CaO5 cluster that serves
as a blueprint to develop superior water‐splitting catalysts for the generation of solar fuels in …