Beyond structural motifs: the frontier of actinide-containing metal–organic frameworks

CR Martin, GA Leith, NB Shustova - Chemical Science, 2021 - pubs.rsc.org
In this perspective, we feature recent advances in the field of actinide-containing metal–
organic frameworks (An-MOFs) with a main focus on their electronic, catalytic …

Stimuli-modulated metal oxidation states in photochromic MOFs

CR Martin, KC Park, GA Leith, J Yu… - Journal of the …, 2022 - ACS Publications
Tuning metal oxidation states in metal–organic framework (MOF) nodes by switching
between two discrete linker photoisomers via an external stimulus was probed for the first …

Cooperative and orthogonal switching in the solid state enabled by metal‐organic framework confinement leading to a thermo‐photochromic platform

GR Wilson, KC Park, GC Thaggard… - Angewandte …, 2023 - Wiley Online Library
Cooperative behavior and orthogonal responses of two classes of coordinatively integrated
photochromic molecules towards distinct external stimuli were demonstrated on the first …

Heterometallic actinide‐containing photoresponsive metal‐organic frameworks: dynamic and static tuning of electronic properties

CR Martin, GA Leith, P Kittikhunnatham… - Angewandte Chemie …, 2021 - Wiley Online Library
Acquiring fundamental knowledge of properties of actinide‐based materials is a necessary
step to create new possibilities for addressing the current challenges in the nuclear energy …

Green, Safe, and Reliable Synthesis of Bimetallic MOF‐808 Nanozymes With Enhanced Aqueous Stability and Reactivity for Biological Applications

C Simms, A Mullaliu, F de de Azambuja, G Aquilanti… - Small, 2024 - Wiley Online Library
Bimetallic metal‐organic frameworks (MOFs) are promising nanomaterials whose reactivity
towards biomolecules remains challenging due to issues related to synthesis, stability …

Nanochannel-based {BaZn}–organic Framework for Catalytic Activity on the Cycloaddition Reaction of Epoxides with CO 2 and Deacetalization-knoevenagel …

H Lv, L Fan, H Chen, X Zhang, Y Gao - Dalton Transactions, 2022 - pubs.rsc.org
Herein, the rare combination of BaII (5s) and ZnII (3d) in the presence of the structure-
oriented TDP6− ligand generated the nanochannel-based hybrid material {[(CH3) 2NH2] 2 …

Advance of Single‐Atom Catalysts Confined into Pristine Metal‐Organic Frameworks and their Energy‐Related Applications

Q Mo, C Chen, S Li, J Liu, L Zhang, CY Su - ChemCatChem, 2024 - Wiley Online Library
Metal single‐atom catalysts (SACs) play an essential role in small molecule related energy
conversion. Metal‐organic frameworks (MOFs), which contain the highly ordered arrays of …

Integrating Compositional and Structural Diversity in Heterometallic Titanium Frameworks by Metal Exchange Methods

EP Gómez-Oliveira, J Castells-Gil… - Journal of the …, 2024 - ACS Publications
The increasing use of Metal–Organic Frameworks (MOFs) in separation, catalysis, or
storage is linked to the targeted modification of their composition or porosity metrics. While …

Lanthanide-mediated tuning of electronic and magnetic properties in heterotrimetallic cyclooctatetraenyl multidecker self-assemblies

Z Zhou, J McNeely, J Greenough, Z Wei, H Han… - Chemical …, 2022 - pubs.rsc.org
The synthesis of a novel family of homoleptic COT-based heterotrimetallic self-assemblies
bearing the formula [LnKCa (COT) 3 (THF) 3](Ln (III)= Gd, Tb, Dy, Ho, Er, Tm, and Yb) is …

Water-driven structural transformation in cobalt trimesate metal-organic frameworks

J Ethiraj, V Surya, P Selvam, JG Vitillo - Energies, 2021 - mdpi.com
We report on the synthesis and the characterization of a novel cobalt trimesate metal-
organic framework, designated as KCL-102. Powder X-ray diffraction pattern of KCL-102 is …