Phosphorus-containing fluorophores provide a versatile framework for tailoring
photophysical properties, enabling the design of advanced fluorogenic materials for various …

Despite significant advances, metal‐catalyzed hydrophosphination has ample room for
discovery, growth, and development. Many of the key successes in metal‐catalyzed …

Catalytic double hydrophosphination of internal alkynes and primary phosphines is possible
using a zirconium complex,[κ5-N, N, N, N, C-(Me3SiNCH2CH2) 2NCH2CH2NSiMe2CH] Zr …

The syntheses of highly fluorescent analogues of PPh3 and PhPCy2 based on the Bodipy
chromophore are described. The ligands have been incorporated into two-to four-coordinate …

Primary acyl‐phosphines are scarce in the literature. Here we show that the reaction of
Ph3GePCO with the ylide Ph3PCH2 proceeds to give the species Ph3PCHC (O) PH …

Direct unequal C–H bond difunctionalization of phosphorylated diamantane was achieved
in high yield from the corresponding phosphonates. Reduction of the functionalized …

Zirconium-catalyzed alkene hydrophosphination and dehydrocoupling with an air-stable,
fluorescent primary phosphine 8-[(4-phosphino) phenyl]-4, 4-dimethyl-1, 3, 5, 7-tetramethyl …

Abstract Treatment of 8‐NH2‐BODIPY, 1 a,(BODIPY= boron, difluoro [2‐[(2H‐pyrrol‐2‐
ylidene‐κN) methyl]‐1H‐pyrrolato‐κN]‐) with NaH, followed by addition of acylchlorides, R …