The basicities of simple organic bases–aliphatic and aromatic amines, amidines,
phosphazenes, as well as saturated and unsaturated nitrogen heterocycles–are examined …

The development of new or more sustainable, active, efficient, controlled, and selective
polymerization reactions or processes continues to be crucial for the synthesis of important …

Acids and bases are ubiquitous. Sometimes, it is essential to know the accurate strength (pK
a values) of the acids/bases to work with, but sometimes just acidity/basicity order is enough …

Conspectus Cyclopropenium ions are the smallest class of aromatic compounds, satisfying
Hückel's rules of aromaticity with two π electrons within a three-membered ring. First …

Conspectus One of the constant challenges of synthetic chemistry is the molecular design
and synthesis of nonionic, metal-free superbases as chemically stable neutral organic …

Starting from the dinickel (II) dihydride complex [ML (Ni–H) 2](1 M), where L3–is a bis
(tridentate) pyrazolate-bridged bis (β-diketiminato) ligand and M+ is Na+ or K+, a series of …

Herein, we describe the catalytic hydrogenation of CO2 to formate with (PNP) Mn–H (PNP=
2, 6-bis (di-tert-butylphosphinomethyl) pyridine; Mn= Mn (CO) 2). Contrary to the established …

In this work we explored the relationship between the structure and solvent effects on the
basicity of a large selection of conjugated N‐heterocyclic nitrogen bases in different media …

Carbide complexes remain a rare class of molecules. Their paucity does not reflect
exceptional instability but is rather due to the generally narrow scope of synthetic …

The Co (− I) dihydrogen complexes,[(η2-H2) CoML]−, where ML is the group 13
metalloligand, N (o-(NCH2PiPr2) C6H4) 3M, and M is Al, Ga, or In, were previously reported …