Defect-enabling zirconium-based metal–organic frameworks for energy and environmental remediation applications

S Daliran, AR Oveisi, CW Kung, U Sen… - Chemical Society …, 2024 - pubs.rsc.org
This comprehensive review explores the diverse applications of defective zirconium-based
metal–organic frameworks (Zr-MOFs) in energy and environmental remediation. Zr-MOFs …

MOF-enabled confinement and related effects for chemical catalyst presentation and utilization

J Liu, TA Goetjen, Q Wang, JG Knapp… - Chemical Society …, 2022 - pubs.rsc.org
A defining characteristic of nearly all catalytically functional MOFs is uniform, molecular-
scale porosity. MOF pores, linkers and nodes that define them, help regulate reactant and …

Water-enhanced direct air capture of carbon dioxide in metal–organic frameworks

OIF Chen, CH Liu, K Wang… - Journal of the …, 2024 - ACS Publications
We have developed two series of amine-functionalized zirconium (Zr) metal–organic
framework-808 (MOF-808), which were produced by postsynthetic modifications to have …

MOFs with bridging or terminal hydroxo ligands: Applications in adsorption, catalysis, and functionalization

I Ahmed, MMH Mondol, MJ Jung, GH Lee… - Coordination Chemistry …, 2023 - Elsevier
Metal-organic frameworks (MOFs) are popular porous materials prepared from metallic
species and organic linkers via the formation of coordination bonds. The applications and …

Cerium based UiO-66 MOF as a multipollutant adsorbent for universal water purification

RM Rego, G Sriram, KV Ajeya, HY Jung… - Journal of hazardous …, 2021 - Elsevier
Herein, we demonstrate the use of cerium (Ce)-UiO-66 metal organic framework (MOF) for
the removal of a variety of potentially toxic pollutants. The Ce-UiO-66 MOF, with similar …

Synthesis and catalytic application of defective MOF materials

Y Shan, G Zhang, Y Shi, H Pang - Cell Reports Physical Science, 2023 - cell.com
Metal-organic framework (MOF) backbone materials, as nanoporous materials, have
outstanding performance in studies on adsorption and catalysis by virtue of their high …

Machine learning the quantum-chemical properties of metal–organic frameworks for accelerated materials discovery

AS Rosen, SM Iyer, D Ray, Z Yao, A Aspuru-Guzik… - Matter, 2021 - cell.com
The modular nature of metal–organic frameworks (MOFs) enables synthetic control over
their physical and chemical properties, but it can be difficult to know which MOFs would be …

Catalysis by metal organic frameworks: perspective and suggestions for future research

D Yang, BC Gates - Acs Catalysis, 2019 - ACS Publications
Metal organic frameworks (MOFs) have drawn wide attention as potential catalysts, offering
high densities of catalytic sites in high-area porous solids, some with stabilities at high …

Generating catalytic sites in UiO-66 through defect engineering

X Feng, HS Jena, C Krishnaraj, K Leus… - … Applied Materials & …, 2021 - ACS Publications
UiO-66 is regarded as an epitome of metal–organic frameworks (MOFs) because of its
stability. Defect engineering has been used as a toolbox to alter the performance of MOFs …

The chemistry and applications of hafnium and cerium (IV) metal–organic frameworks

Z Hu, Y Wang, D Zhao - Chemical Society Reviews, 2021 - pubs.rsc.org
The coordination connection of organic linkers to the metal clusters leads to the formation of
metal–organic frameworks (MOFs), where the metal clusters and ligands are spatially …