[FeFe]-Hydrogenases: maturation and reactivity of enzymatic systems and overview of biomimetic models

JT Kleinhaus, F Wittkamp, S Yadav… - Chemical Society …, 2021 - pubs.rsc.org
While hydrogen plays an ever-increasing role in modern society, nature has utilized
hydrogen since a very long time as an energy carrier and storage molecule. Among the …

Metal–organic and covalent organic frameworks as single-site catalysts

SMJ Rogge, A Bavykina, J Hajek, H Garcia… - Chemical Society …, 2017 - pubs.rsc.org
Heterogeneous single-site catalysts consist of isolated, well-defined, active sites that are
spatially separated in a given solid and, ideally, structurally identical. In this review, the …

Enzymnachbildungen auf der Basis supramolekularer Koordinationschemie

MJ Wiester, PA Ulmann, CA Mirkin - Angewandte Chemie, 2011 - Wiley Online Library
In der aktuellen supramolekularen Koordinationschemie können makromolekulare
Komplexe mit Enzymeigenschaften synthetisiert werden. Dieser Aufsatz behandelt solche …

Synthesis of diiron (I) dithiolato carbonyl complexes

Y Li, TB Rauchfuss - Chemical reviews, 2016 - ACS Publications
Virtually all organosulfur compounds react with Fe (0) carbonyls to give the title complexes.
These reactions are reviewed in light of major advances over the past few decades, spurred …

Structural and functional analogues of the active sites of the [Fe]-,[NiFe]-, and [FeFe]-hydrogenases

C Tard, CJ Pickett - Chemical reviews, 2009 - ACS Publications
This article sets out to review the chemistry relating to the synthesis of structural and
functional analogues of the three classes of hydrogenases. This chemistry has grown …

Enzyme mimics based upon supramolecular coordination chemistry

MJ Wiester, PA Ulmann… - Angewandte Chemie …, 2011 - Wiley Online Library
Recent advances in supramolecular coordination chemistry have allowed chemists to
synthesize macromolecular complexes that exhibit various properties intrinsic to enzymes …

Hydrogen production by molecular photocatalysis

AJ Esswein, DG Nocera - Chemical reviews, 2007 - ACS Publications
A great technological challenge facing our global future is the development of a secure,
clean, and renewable energy source. 1-4 Rising standards of living in a growing world …

Molecular systems for light driven hydrogen production

WT Eckenhoff, R Eisenberg - Dalton Transactions, 2012 - pubs.rsc.org
Recent work towards the production of hydrogen via reduction of protons is described. Most
of the systems examined in this perspective use a molecular chromophore for harvesting …

Small molecule mimics of hydrogenases: hydrides and redox

F Gloaguen, TB Rauchfuss - Chemical Society Reviews, 2009 - pubs.rsc.org
This tutorial review is aimed at chemical scientists interested in understanding and
exploiting the remarkable catalytic behavior of the hydrogenases. The key structural features …

Artificial Photosynthesis: From Molecular Catalysts for Light‐driven Water Splitting to Photoelectrochemical Cells

ES Andreiadis, M Chavarot‐Kerlidou… - Photochemistry and …, 2011 - Wiley Online Library
Photosynthesis has been for many years a fascinating source of inspiration for the
development of model systems able to achieve efficient light‐to‐chemical energetic …