Endohedral fullerenes

AA Popov, S Yang, L Dunsch - Chemical reviews, 2013‏ - ACS Publications
One of the attractive properties of the hollow carbon clusters, known as fullerenes, is the
possibility to use them as robust containers for other species. Although an IUPAC …

Endohedral metallofullerene molecular nanomagnets

Z Hu, S Yang - Chemical Society Reviews, 2024‏ - pubs.rsc.org
Magnetic lanthanide (Ln) metal complexes exhibiting magnetic bistability can behave as
molecular nanomagnets, also known as single-molecule magnets (SMMs), suitable for …

When metal clusters meet carbon cages: endohedral clusterfullerenes

S Yang, T Wei, F ** - Chemical society reviews, 2017‏ - pubs.rsc.org
Fullerenes have the characteristic of a hollow interior, and this unique feature triggers
intuitive inspiration to entrap atoms, ions or clusters inside the carbon cage in the form of …

Current status and future developments of endohedral metallofullerenes

X Lu, L Feng, T Akasaka, S Nagase - Chemical Society Reviews, 2012‏ - pubs.rsc.org
Endohedral metallofullerenes (EMFs), a new class of hybrid molecules formed by
encapsulation of metallic species inside fullerene cages, exhibit unique properties that differ …

[ספר][B] Organic electrochemistry

O Hammerich, B Speiser - 2016‏ - api.taylorfrancis.com
Organic electrochemistry is concerned with the reduction and oxidation of organic molecules
at electrodes. Although it is now more than 200 years ago that the so-called Volta pile was …

Chemical, electrochemical, and structural properties of endohedral metallofullerenes

MN Chaur, F Melin, AL Ortiz… - Angewandte Chemie …, 2009‏ - Wiley Online Library
Ever since the first experimental evidence of the existence of endohedral metallofullerenes
(EMFs) was obtained, the search for carbon cages with encapsulated metals and small …

The electrochemical behavior of cerium (III/IV) complexes: Thermodynamics, kinetics and applications in synthesis

NA Piro, JR Robinson, PJ Walsh, EJ Schelter - Coordination Chemistry …, 2014‏ - Elsevier
A key characteristic of the element cerium is its reversible redox chemistry between trivalent
and tetravalent forms, which is central to the application of cerium in synthetic and materials …

Chemistry of endohedral metallofullerenes: the role of metals

X Lu, T Akasaka, S Nagase - Chemical Communications, 2011‏ - pubs.rsc.org
Recent breakthroughs achieved in the chemical functionalization of endohedral
metallofullerenes (EMFs), especially single crystallographic X-ray characterizations of their …

Bonding in endohedral metallofullerenes as studied by quantum theory of atoms in molecules

AA Popov, L Dunsch - Chemistry–A European Journal, 2009‏ - Wiley Online Library
Metal–cage and intracluster bonding was studied in detail by quantum theory of atoms in
molecules (QTAIM) for the four major classes of endohedral metallofullerenes (EMFs) …

Sc2S@Cs(10528)-C72: A Dimetallic Sulfide Endohedral Fullerene with a Non Isolated Pentagon Rule Cage

N Chen, CM Beavers, M Mulet-Gas… - Journal of the …, 2012‏ - ACS Publications
A non isolated pentagon rule metallic sulfide clusterfullerene, Sc2S@ C s (10528)-C72, has
been isolated from a raw mixture of Sc2S@ C2 n (n= 35–50) obtained by arc-discharging …